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and 12.0 Hz, H-1), 3.15 (t, 1H, J=11.5 and 12.5 Hz,
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5·HCl: [h]589=+3.5 (c 1.7, MeOH:H2O 1:2); 1H NMR
(500 MHz, D2O): l 4.14–4.12 (m, 1H, H-2), 4.10–4.07
(m, 2H, H-3, H-4), 4.01–3.92 (m, 2H, H-6 and H-6%),
3.69–3.66 (m, 1H, H-5), 3.51 (dd, 1H, J=3.0 and 13.75
Hz, H-1), 3.43 (dd, 1H, J=3.5 and 13.5 Hz, H-1%); 13C
NMR (75 MHz, CDCl3): l 67.81, 67.62, 66.59, 58.99,
56.80, 45.47.
1
2·HCl: [h]589=−9.9 (c 1.5, MeOH), H NMR (500 MHz,
D2O): l 4.30–4.29 (m, 1H, H-2), 4.04 (dd, 1H, J=3.0 and
12.5 Hz, H-6), 3.93–3.87 (m, 2H, H-6% and H-4), 3.75
(dd, 1H, J=3.5 and 9.5 Hz, H-3), 3.47 (dd, 1H, J=2.5
and 13.7 Hz, H-1), 3.30 (dd, 1H, J=1.0 and 13.5 Hz),