Novel Rearrangement of 5,6-Disubstituted Bicyclooctan-2-ones with AlCl3. Application to Total Synthesis of (+/-)-5-Oxosilphiperfol-6-ene and (+/-)-Silphiperfol-6-ene

DOI: 10.1021/ja00192a031

Source and publish data:

Journal of the American Chemical Society p. 3707 - 3712 (1989)

Update date:2022-08-04

Topics:

Authors:

Kakiuchi, Kiyomi

Ue, Masaki

Tsukahara, Hiroshi

Shimizu, Toshihiro

Miyao, Tomoya

et al. et al.

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Article abstract of DOI:10.1021/ja00192a031

The acid-catalyzed rearrangement of bi- and tricyclic cyclobutyl ketones 8-20 having a bicyclo<4.2.0>octan-2-one moiety with AlCl3 was studied to elucidate the scope and limitations of the novel rearrangement by which the tricyclic ketone 1 gave the angul

Full text of DOI:10.1021/ja00192a031

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