Tetrahedron p. 11069 - 11086 (1997)
Update date:2022-08-02
Topics:
Owada, Yufu
Matsuo, Takeshi
Iwasawa, Nobuharu
A novel transformation of 1-(1,2-propadienyl)cyclopropanols into substituted 1,4-hydroquinones has been developed utilizing the interaction of 1,2-propadienes and octacarbonyldicobalt (Co2(CO)8). This reaction was applied to the synthesis of vitamin E and K analogs.
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