
Journal of Coordination Chemistry p. 856 - 864 (2012)
Update date:2022-08-03
Topics:
Wen, Hui-Liang
Wang, Tao-Tao
Liu, Chong-Bo
He, Min
Wang, Yuan-Xing
Two new transition metal complexes, [Zn(Hdiba)2(H2O)] ·H2O (1) and [Cu(Hdiba)2] (2) (H 2diba=2-(4,5-diphenyl-1H-imidazol-2-yl)benzoic acid), were synthesized and characterized by IR, elemental analysis, and single-crystal X-ray diffraction. Complex 1 exhibits a monomeric structure, while 2 displays a dimeric structure. Both structures extend to 2-D supramolecular networks via hydrogen bonds. Thermal stabilities of 1 and 2 and photophysical properties of 1 are also discussed.
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