Bulletin of the Chemical Society of Japan p. 1163 - 1170 (1981)
Update date:2022-08-02
Topics: Oxygen Activation
Watanabe, Yoshihito
Numata, Tatsuo
Iyanagi, Takashi
Oae, Shigeru
The oxidation of alkyl sulfides, sulfoxides, and sulfones was examined with either rabbit liver microsomes or a reconstituted system containing purified cytochrome P-450, S-dealkylation being found to take place more readily with alkyl sulfides bearing a higher acidic α-hydrogen.Similar results were obtained in the oxidation of alkyl sulfides by hydroxyl radical.Both S-dealkylation and S-oxygenation products are presumed to be formed via the cation radical intermediate.
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