
Tetrahedron Letters p. 8419 - 8422 (1995)
Update date:2022-09-26
Topics:
Demonceau, A.
Lemoine, C. A.
Noels, A. F.
Chizhevsky, I. T.
Sorokin, P.V.
OsCl2(PPh3)3 is a cyclopropanation catalyst using ethyl diazoacetate with a variety of activated alkenes; OsCl2(PPh3)3 is however less active than RuCl2(PPh3)3 for the decomposition of the diazo reagent and the subsequent cyclopropanation.
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