Deracemization of a Phosphine Oxide via Enantioselective Protonation

DOI: 10.1021/jo00101a008

Source and publish data:

Journal of Organic Chemistry p. 6517 - 6518 (1994)

Update date:2022-08-05

Topics:

Authors:

Vedejs, E.

Garcia-Rivas, J. A.

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Article abstract of DOI:10.1021/jo00101a008

Treatment of the phosphine oxide anion 2 with the keto aniline 3c affords (S)-1 with 81-83percent ee, and one crystallization upgrades the material to (S)-1 with > 99percent ee (78percent overall yield).

Full text of DOI:10.1021/jo00101a008

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