Interactions between Sulphide Minerals and Alkylxanthate Ions Part 4.-Vibrational Spectroscopic and Calorimetric Study of the Interactions between Galena and Synthetic Lead(II) Sulphide, and Alkylxanthate Ions in Aqueous, Acetone and Acetonitrile Solutions

DOI: 10.1039/ft9918702779

Source and publish data:

Journal of the Chemical Society - Faraday Transactions p. 2779 - 2784 (1991)

Update date:2022-08-03

Topics:

Authors:

Persson, Per

Persson, Ingmar

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/ft9918702779

The reactions between galena and synthetic lead(II) sulphide powders, and potassium alkylxanthates have been studied in aqueous, acetone and acetonitrile solutions.Acetone and acetonitrile have been used since potassium and lead(II) alkylxanthates are soluble in these solvents.Qualitative analysis of the alkylxanthate species present on the surfaces of galena and lead(II) sulphide after treatment with alkylxanthate ions has been made by means of diffuse reflectance infrared Fourier transform (DRIFT) spectroscopy.Solid lead(II) alkylxanthate is formed on oxidized galena and lead(II) sulphide surfaces.Alkylxanthate ions are co-ordinated to lead sites in the ultimate surface layer as alkylxanthate complexes on synthetic lead(II) sulphide surfaces when soluble lead(II) compounds are removed.Two types of complex adsorbed onto galena and lead(II) sulphide surfaces have been found.One of these complexes resembles similar complexes on zinc(II) and cadmium(II) sulphide surfaces.This chemisorbed complex is formed in all solvents studied.The other kind of complex is formed only in acetone and acetonitrile solutions.It displays a unique vibrational spectrum and it is formed in a non-exothermic reaction.This complex may result from an electrostatic interaction between a charged particle and alkylxanthate ions.

Full text of DOI:10.1039/ft9918702779

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:dithiocarbonic acid O-ethyl ester; lead (II)-salt

Cas No:55671-63-1

R&D Labs maybe for 55671-63-1

Changsha Yihai Chemical Technology Co.,ltd

website:http://www.cs-yihai.com/

Contact:0731- 85620465

Address:Room 23005, unit 2, the northern building of Xiangsong international building , NO.259 Shaoshan Road , Changsha , Hunan, China.(mainland)
TLS PHARMACEUTICAL CO.,LTD

Contact:0833-5590788/5590338/5590055

Address:Victory in the town of Red Star Village,Mount Emei City,industrial concentration area storage processing logistics parkpark
Shanghai Hanshare Industry Co.,Ltd.

Contact:86 21 20960688

Address:RM902-903,Building E, Wanda Plaza,No.26,Zhoukang Road, Pudong District, Shanghai, China
Shanghai HengXun Pharmaceutical Tech. Co., Ltd.

Contact:86-86-52730756

Address:Room 603, No. 240, Tianmuzhong Road, Zhabei, Shanghai, China
Beijing Tianjia Chemical Science & Technology Co.,Ltd

Contact:86-0550-2392698

Address:No.388, Shiliang Road (East),

Relevant to this article

Doi:10.1039/P19750000614
()
ENDOR of NO-ligated cytochrome c′

Doi:10.1021/ja055323f
(2006)
Doi:10.1021/jo01178a010
(1945)
Stereoselective synthesis of highly substituted γ-lactams by the [3+2] annulation of α-siloxy allylic silanes with chlorosulfonyl isocyanate

Doi:10.1021/ol060596g
(2006)
Nickel(II) complexes with amide ligands: Oxidative dehydrogenation of the amines in a tetradentate diamide-diamine ligand

Doi:10.1039/b107378h
(2002)
Radical Desulfur-Fragmentation and Reconstruction of Enol Triflates: Facile Access to α-Trifluoromethyl Ketones

Doi:10.1002/anie.201608507
(2017)

Article Doi