Tetrahedron Letters p. 4241 - 4242 (1980)
Update date:2022-08-03
Topics:
Schubert
Green, David C.
Monomeric p-dimethylamino-α-bromostyrene undergoes SNl increasingly slowly in 60 to 91% dioxane. Reaction is catalyzed by HClO4, NaOH and NaClO4. Dimer 11 reverts to monomer I in 91% dioxane. There is only a small solvent effect on the solvolysis rate of II.
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(1975)Doi:10.1016/j.tetlet.2016.09.076
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(2001)