Journal of Fluorine Chemistry p. 129 - 138 (1988)
Update date:2022-08-04
Topics:
Krespan, Carl G.
F-alkyliron tetracarbonyl iodides are convenient sources of terminal vinyl iodides by a simple pyrolytic technique.The precursors to the F-alkyliron tetracarbonyl iodides, an F-alkyl iodide and iron pentacarbonyl, can be used to generate F-alkyl radicals capable, for example, of F-alkylating benzene in moderate yield.Mechanisms for these transformations are proposed.
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