Homolytic Reactions of Ligated Boranes. Part 18. The Scope of Enantioselective Hydrogen-atom Abstraction by Chiral Amine-Boryl Radicals for Kinetic Resolution under Conditions of Polarity Reversal Catalysis

DOI: 10.1039/P19940001033

Source and publish data:

Journal of the Chemical Society. Perkin transactions I p. 1033 - 1042 (1994)

Update date:2022-09-26

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Authors:

Dang, Hai-Shan

Diart, Valerie

Roberts, Brian P.

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Article abstract of DOI:10.1039/P19940001033

A variety of new and previously-known optically active amine-borane complexes have been used as polarity reversal catalysts for the kinetic resolution of representative racemic carbonyl-containing compounds.The key step involves enantioselective abstracti

Full text of DOI:10.1039/P19940001033

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