Homolytic Reactions of Ligated Boranes. Part 18. The Scope of Enantioselective Hydrogen-atom Abstraction by Chiral Amine-Boryl Radicals for Kinetic Resolution under Conditions of Polarity Reversal Catalysis

DOI: 10.1039/P19940001033

Source and publish data:

Journal of the Chemical Society. Perkin transactions I p. 1033 - 1042 (1994)

Update date:2022-09-26

Topics:

Authors:

Dang, Hai-Shan

Diart, Valerie

Roberts, Brian P.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/P19940001033

A variety of new and previously-known optically active amine-borane complexes have been used as polarity reversal catalysts for the kinetic resolution of representative racemic carbonyl-containing compounds.The key step involves enantioselective abstracti

Full text of DOI:10.1039/P19940001033

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:dihydro-3-trimethylsiloxy-4,4-dimethylfuran-2(3H)-one

Cas No:56193-78-3

R&D Labs maybe for 56193-78-3

Huayang chemical Co., LTD

Contact:+86-18653358619

Address:zibo
Cerametek Materials（ShenZhen）Co., Ltd.

Contact:+86-755-2324.2554

Address:A3-#9, YongChuan Street, Suite 501
Shanghai TBBMed Co.,Ltd

website:http://www.tbbmed.com

Contact:86--21-50498136

Address:Room 6002, Building 7-1, No.160 Basheng Road,Pudong Area,Shanghai China
Hangzhou Zyter Biological & Chemical Technology Co., Ltd.

website:http://www.zyterpharm.com

Contact:+86-18858184290

Address:West Wenyi Road, Cangqian, Yuhang
Binzhou Holly Pharmaceutical Co.,Ltd.

Contact:74517

Address:No.15 Dapu Road,Huangpu District Shanghai,P.R.China

Relevant to this article

Doi:10.1016/S0022-328X(00)80345-9
(1975)
Easily processable phenylene-thiophene-based organic field-effect transistors and solution-fabricated nonvolatile transistor memory elements

Doi:10.1021/ja035143a
(2003)
Homogeneous Hydrogenation with a Cobalt/Tetraphosphine Catalyst: A Superior Hydride Donor for Polar Double Bonds and N-Heteroarenes

Doi:10.1021/jacs.9b11070
(2019)
Reaction of isatin-1-acetamides with alkoxides: Synthesis of novel 1,4-dihydro-3-hydroxy-4-oxo-2-quinolinecarboxamides

Doi:10.1055/s-2007-965949
(2007)
Evaluation of asymmetric Diels-Alder approaches for the synthesis of the cyclohexene subunit of CP-225,917 and CP-263,114

Doi:10.1016/S0040-4039(03)00835-9
(2003)
Operational control of stereoselectivity during the enzymatic hydrolysis of racemic organophosphorus compounds

Doi:10.1021/ja035625m
(2003)

Article Doi