Highly regioselective rearrangement of 2-substituted vinylepoxides catalyzed by gallium(III) triflate

DOI: 10.1021/jo050810z

Source and publish data:

Journal of Organic Chemistry p. 6537 - 6540 (2005)

Update date:2022-08-04

Topics:

Authors:

Deng, Xian-Ming

Sun, Xiu-Li

Tang, Yong

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo050810z

Gallium(III) triflate catalyzed the rearrangement of 2-sub-stituted vinylepoxides into β,γ-unsaturated carbonyl compounds with high regio- and chemoselectivity (>97/3) in low catalyst loading (1-5 mol%). The alkyl-substituted trimethylsilylvinyl epoxides

Full text of DOI:10.1021/jo050810z

Products guided by the article

Product name:p-Chlorphenyl-2-buten-2-al

Cas No:56790-73-9

R&D Labs maybe for 56790-73-9

Joyochem Co., Ltd.

website:https://sdjingyuan.lookchem.com/

Contact:86-531-82687998

Address:Factory Building 11, Jinan Comprehensive free trade zone, Shandong, China
Shanghai Dianyang Industry Co.,ltd

Contact:+86 21 6492 4669

Address:Chejing RD, Songjiang District, Shanghai, China
Tianjin Tongde Biological Technology Co., Ltd.

Contact:86-22-23309138

Address:Room 402, bulidingE3 Detection certification park, XiQingDistrict, Tianjin City
Antimex Chemical Limied

website:http://www.antimex.com

Contact:0086-21-50563169

Address:Room1027,No.Jinyu Road,Pudong
Jiangsu Mingchem Corporation

website:http://www.mingchem.com/en/index

Contact:0519-85170101-802

Address:Fifth Floor,B of Beihua Buliding,520 Road of Science and Education City,Changwu middle road NO.801,Wujin District,Changzhou,Jiangsu province

Relevant to this article

CONVERSION OF RADICAL CATIONS OF POLYFLUOROAROMATIC COMPOUNDS INTO DIHYDROAROMATIC PRODUCTS IN THE PRESENSE OF FLUORIDE AND CHLORIDE ANIONS

Doi:10.1016/S0040-4039(00)94030-9
(1983)
The development of new triazole based inhibitors of tumor necrosis factor-α (TNF-α) production

Doi:10.1016/S0960-894X(03)00238-5
(2003)
Teaching old indicators new tricks: A colorimetric chemosensing ensemble for tartrate/malate in beverages

Doi:10.1002/(SICI)1521-3773(19991216)38:24<3666::AID-ANIE3666>3.0.CO;2-E
(1999)
Some observations on the base-catalyzed cyclocondensation of 2,6-Dihalobenzaldehydes, ethyl cyanoacetate, and thiourea

Doi:10.1080/00397910903098730
(2010)
Strategy for Overcoming Full Reversibility of Intermolecular Radical Addition to Aldehydes: Tandem C-H and C-O Bonds Cleaving Cyclization of (Phenoxymethyl)arenes with Carbonyls to Benzofurans

Doi:10.1021/acs.orglett.8b01207
(2018)
Cyclopentasilanderivate mit Uebergangselementen

Doi:10.1016/0022-328X(94)84106-3
(1994)

Article Doi