Advanced Synthesis and Catalysis p. 222 - 226 (2021)
Update date:2022-08-03
Topics:
Peng, Xiaopeng
Yang, Yang
Luo, Bingling
Wen, Shijun
Huang, Peng
Starting from cyclic diaryliodoniums and terminal alkenes, a diverse set of fluorenes is conveniently constructed. The reactions catalyzed by palladium undergo one conventional Mizoroki-Heck reaction and one reductive Heck reaction. The scope of alkenes is general, leading to 29 fluorenes which would expand the structural diversity of fluorene reservoir. (Figure presented.).
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