A NOVEL APPROACH TO PROSTAGLANDINS FROM THE COREY LACTONE INVOLVING BF3-MEDIATED REACTIONS OF A SULPHONE AND ALDEHYDES

DOI: 10.1016/S0040-4039(01)80897-2

Source and publish data:

Tetrahedron Letters p. 5597 - 5600 (1985)

Update date:2022-08-04

Topics:

Authors:

Achmatowicz, B.

Baranowska, E.

Daniewski, A. R.

Pankowski, J.

Wicha, J.

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Article abstract of DOI:10.1016/S0040-4039(01)80897-2

Transformation of the diol 1 via epimeric sulphones 7 to PGF_2α is described.Alkylation of lithiated sulphones 7 with aldehydes 8a, 8b or 8c in the presence of BF3 efficiently gives corresponding adducts.

Full text of DOI:10.1016/S0040-4039(01)80897-2

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