Journal of the Chemical Society. Chemical communications p. 1333 - 1335 (1987)
Update date:2022-08-03
Topics:
Hagiwara, Hisahiro
Okano, Akihiro
Akama, Tsutomu
Uda, Hisashi
The trimethylsilyl enol ethers of 1-acetylcyclohexenes undergo a Lewis-acid-assisted one-pot annelation reaction with α,β-unsaturated carbonyl compounds to produce 5-substituted 2-decalones; the application of this reaction has enabled a synthesis of (+/-)-ε-cadinene (12).
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