Journal of Organic Chemistry p. 5460 - 5464 (1985)
Update date:2022-07-30
Topics:
Bauer, Phillip E.
Nelson, David A.
Watt, David S.
Reibenspies, Joseph H.
Anderson, Oren P.
et al.
The rearrangement of 5-cholestene to (20ξ)-13(17)-diacholestenes, separation of C-20 epimers, and further reduction provided an unambiguous synthesis of the biomarkers (20R)- and (20S)-13β,17α(H)-diacholestanes.Repetition of this sequence using (24R)-5-campestene or (24R)-5-stigmastene provided the analogous C28 and C29 diasteranes.
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Doi:10.1021/jacs.7b08064
(2017)Doi:10.1002/aoc.3443
(2016)Doi:10.1021/om030154y
(2003)Doi:10.1002/jlcr.2590110320
(1975)Doi:10.1021/jo01131a009
(1953)Doi:10.1007/BF00924712
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