
Tetrahedron Letters p. 5629 - 5632 (1986)
Update date:2022-08-05
Topics:
Kiyooka, Syun-ichi
Yamashita, Tsuneo
Tashiro, Jun-ichi
Takano, Kazuyuki
Uchio, Yasuto
A novel reaction of ketone enolate with dimethylformamide (DMF) to give 1,5-diketone has been found.It is a dimerization of ketone enolates accompanying the incorporation of one-methylene from DMF.
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