ONE-METHYLENE INCORPORATED DIMERIZATION REACTION OF KETONE ENOLATES. 1. A NEW ROUTE TO 1,5-DIKETONES FROM KETONES HAVING α-ACTIVE HYDROGEN ON ONE SIDE

DOI: 10.1016/S0040-4039(00)85285-5

Source and publish data:

Tetrahedron Letters p. 5629 - 5632 (1986)

Update date:2022-08-05

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Authors:

Kiyooka, Syun-ichi

Yamashita, Tsuneo

Tashiro, Jun-ichi

Takano, Kazuyuki

Uchio, Yasuto

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Article abstract of DOI:10.1016/S0040-4039(00)85285-5

A novel reaction of ketone enolate with dimethylformamide (DMF) to give 1,5-diketone has been found.It is a dimerization of ketone enolates accompanying the incorporation of one-methylene from DMF.

Full text of DOI:10.1016/S0040-4039(00)85285-5

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