Selective Allylic Electro-oxidation of α- and β-Ionones

DOI: 10.1039/c39870000041

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 41 - 42 (1987)

Update date:2022-08-04

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Authors:

Guirado, Antonio

Moss, Gerard P.

Utley, James H. P.

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Article abstract of DOI:10.1039/c39870000041

Allylic ring substitution of α- and β-ionones by, respectively, anodically generated cobalt(III)acetate and bromine, is selective and efficient; in contrast direct anodic oxidation is unselective but provides a route to the novel, rearranged, carotenoid end group (7).

Full text of DOI:10.1039/c39870000041

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