STEREOSELECTIVE SYNTHESIS OF TRANS-HYDRINDANES BY INTERNAL VINYLSILANE ACYLATION

DOI: 10.1016/S0040-4039(01)91083-4

Source and publish data:

Tetrahedron Letters p. 3591 - 3594 (1984)

Update date:2022-08-03

Topics:

Authors:

Fukuzaki, Kentaro

Nakamura, Eiichi

Kuwajima, Isao

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Article abstract of DOI:10.1016/S0040-4039(01)91083-4

trans-Hydrindanediones (1, 3, and 15) have been synthesized in short steps through stereoselective introduction of vinylsilane units onto the cycloalkenones 5 or 10 followed by AgBF4-mediated internal acylation of the vinylsilane moiety.

Full text of DOI:10.1016/S0040-4039(01)91083-4

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