ENANTIOSELECTIVITY IN ENEDIOL-HYDROXYKETONE TAUTOMERIZATION

DOI: 10.1016/S0040-4039(00)88302-1

Source and publish data:

Tetrahedron Letters p. 4209 - 4212 (1983)

Update date:2022-08-05

Topics:

Authors:

Duhamel, Lucette

Launay, Jean-Claude

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Article abstract of DOI:10.1016/S0040-4039(00)88302-1

The conversion of racemic α-hydroxyketone into optically active α-hydroxyketone with e.e. as high as 80percent and in good yield is reported.This is accomplished by a low temperature enantioselective protonation of the enediol using (2R,3R) O,O-dipivaloyltartaric acid.

Full text of DOI:10.1016/S0040-4039(00)88302-1

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