One-pot SmI2-promoted transformation of carbohydrate derivatives into cyclopentanols

DOI: 10.1016/0040-4039(96)01234-8

Source and publish data:

Tetrahedron Letters p. 5817 - 5820 (1996)

Update date:2022-08-04

Topics:

Authors:

Grove, J.J. Cronje

Holzapfel, Cedric W.

Williams, D. Bradley G.

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Article abstract of DOI:10.1016/0040-4039(96)01234-8

Selectively functionalised carbohydrate derivatives underwent SmI₂-promoted Grob-fragmentation reactions. This was followed by an in situ, stereocontrolled SmI₂-mediated cyclisation to afford the corresponding cyclopentanols.

Full text of DOI:10.1016/0040-4039(96)01234-8

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