Tetrahedron p. 953 - 956 (1981)
Update date:2022-08-03
Topics:
Arct, J.
Migaj, B.
The reactions of 7,7-dichlorobicyclo-<4.1.0>heptane, 1 with organic bases were carried out in benzene and THF.The reaction course of 1 in nonpolar media is different from that in DMSO; the rearrangements of cyclopropene 3 taking place in the former. 8 is produced by the shift of double bond into the C6 ring.The cyclopropene-carbene isomerization and reactions of carbenes 14 and 15 with alkoxide anions are the probable route leading to the other products.
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Doi:10.1002/chem.201100618
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