Synthese regiospecifique d'amines tertiaires a groupe secondaire bi-insature

Article abstract of DOI:10.1016/0022-328X(89)85018-1

We describe the regiospecific preparation of tertiary amines with a symmetrical (or dissymetrical) doubly unsaturated secondary group, by reaction of an allylic, vinylic or acetylenic organometallic derivative with a dialkylformamido acetal, a chlorinated iminium salt or an alkynyl aminoether.