Journal of Organometallic Chemistry p. 1 - 10 (1989)
Update date:2022-09-26
Topics: SYNTHESE Regiospecifique Amines tertiaires Groupe secondaire Bi-insature Réaction chimique Catalyseur Conditions de réaction Réactifs Produits Chromatographie Analyse spectroscopique
Mesnard, D.
Miginiac, L.
We describe the regiospecific preparation of tertiary amines with a symmetrical (or dissymetrical) doubly unsaturated secondary group, by reaction of an allylic, vinylic or acetylenic organometallic derivative with a dialkylformamido acetal, a chlorinated iminium salt or an alkynyl aminoether.
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Doi:10.1021/jo00883a021
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