Journal of the Chemical Society. Chemical communications p. 119 - 120 (1985)
Update date:2022-07-30
Topics: Ketene silyl acetals Trimethylsilyl trifluoromethanesulfonate
Okano, Kohji
Morimoto, Toshiaki
Sekiya, Minoru
General α-formylation of α,α-disubstituted methyl acetates can be achieved by the reaction of ketene silyl acetals (1) with N-t-butylformimidoyl cyanide (2) in the presence of trimethylsilyl trifluoromethanesulphonate (3) as catalyst followed by hydrolysi
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