Structure Investigations of Group 13 Derivatives of N-Phenylsalicylideneimine

Article abstract of DOI:10.1021/om030331v

The reaction of MMe₃ with 1 molar equiv of N-phenylsalicylideneimine (HsaldPh) yields the O,N-chelate complexes Me ₂M(saldPh) (where M = Al (1), Ga (2), In (3)) in high yields. The reaction of 1 with γ-picoline results in a ligand redistribution reaction and the formation of the five-coordinate complex MeAl(saldPh)₂ (4), while the gallium and indium compounds are stable in the presence of γ-picoline. The resulting compounds have been characterized in a solution by NMR and IR spectroscopy and cryoscopic molecular weight measurements, and their molecular and crystal structure have been determined by X-ray crystallography. Compounds 1 and 2 exist as monomeric tetrahedral complexes, while the indium analogue 3 is dimeric with the In₂(μ-O) ₂ bridges and five-coordinate metal centers. The five-coordinate methylaluminum compound 4 exhibits trigonal-bipyramidal geometry of the metal center. The obtained results show that a Schiff base acts as a strongly coordinating chelate ligand and, in this regard, it resembles the symmetrical acetylacetonato ligand and related β-diketonates. An extended crystal structure analysis reveals that the isostructural crystalline complexes 1 and 2 comprise monomeric four-coordinate molecules linked by C-H _imino...O hydrogen bonds, forming helical chains. Parallel left- and right-handed helices joined by C-H...π interactions give rise to the 3D extended tetragonal framework, with voids filled by solvent molecules. In the crystalline complex 4 the C-H_aryl...O hydrogen bonds organize molecules into H-bonded dimers.

Full text of DOI:10.1021/om030331v

Organometallics 2003, 22, 3773-3780
3773
Str u ctu r e In vestiga tion s of Gr ou p 13 Der iva tives of
N-P h en ylsa licylid en eim in e
J anusz Lewin´ski,*,†,‡ J anusz Zachara,*,† Kazimierz B. Starowieyski,†
Zbigniew Ochal,† Iwona J ustyniak,§ Tomasz Kopec´,† Patryk Stolarzewicz,† and
Maciej Dranka†
Department of Chemistry, Warsaw University of Technology, Noakowskiego 3,
00-664 Warsaw, Poland, and Institute of Physical Chemistry, Polish Academy of Sciences,
01-224 Warsaw, Poland
Received May 5, 2003
The reaction of MMe3 with 1 molar equiv of N-phenylsalicylideneimine (HsaldPh) yields
the O,N-chelate complexes Me2M(saldPh) (where M ) Al (1), Ga (2), In (3)) in high yields.
The reaction of 1 with γ-picoline results in a ligand redistribution reaction and the formation
of the five-coordinate complex MeAl(saldPh)2 (4), while the gallium and indium compounds
are stable in the presence of γ-picoline. The resulting compounds have been characterized
in a solution by NMR and IR spectroscopy and cryoscopic molecular weight measurements,
and their molecular and crystal structure have been determined by X-ray crystallography.
Compounds 1 and 2 exist as monomeric tetrahedral complexes, while the indium analogue
3 is dimeric with the In2(µ-O)2 bridges and five-coordinate metal centers. The five-coordinate
methylaluminum compound 4 exhibits trigonal-bipyramidal geometry of the metal center.
The obtained results show that a Schiff base acts as a strongly coordinating chelate ligand
and, in this regard, it resembles the symmetrical acetylacetonato ligand and related
â-diketonates. An extended crystal structure analysis reveals that the isostructural crystalline
complexes 1 and 2 comprise monomeric four-coordinate molecules linked by C-Himino‚‚‚O
hydrogen bonds, forming helical chains. Parallel left- and right-handed helices joined by
C-H‚‚‚π interactions give rise to the 3D extended tetragonal framework, with voids filled
by solvent molecules. In the crystalline complex 4 the C-Haryl‚‚‚O hydrogen bonds organize
molecules into H-bonded dimers.
In tr od u ction
erization of ethylene4 and methacrylate5 and the ring-
opening polymerization of heterocyclic monomers.6 The
chemistry of group 13 Salen and Salophen derivatives
has been reviewed by Atwood recently.1 We have been
attracted to the study of bidentate Schiff base ligands
in the course of our investigation on the molecular
architecture, bonding, and reactivity of group 13 metal
chelate complexes,7 specifically in studies of the role of
the bidentate ligand nature and interplay of coordina-
tive bonds and hydrogen bonds.7b,8,9 We assumed also
that this group of complexes should be a good basic
Metal complexes of monoanionic, both bidentate and
pendant arm multidentate Schiff bases and related
dianionic ligands such as Salen (ethylenediamine bridged)
and Salophen (o-phenylenediamine-bridged) have played
a very important role in the development of coordination
chemistry for decades.1 In Schiff base complexes, the
coordination environment at the metal center can be
modified by attaching different substituents to the
ligand, which provides a useful range of steric and
electronic properties essential for the fine tuning of
structure and reactivity. Therefore, it is also not sur-
prising that both transition-metal and p-block-metal
derivatives of Schiff bases have been shown to catalyze
a wide variety of reactions.2,3 For example, aluminum-
based complexes, which are of particular relevance to
this paper, have been used as catalysts in the polym-
(4) Cameron, P. A.; Gibson, V. C.; Redshaw, C.; Segal, J . A.; Bruce,
M. D.; White, A. J . P.; Williams, D. J . Chem. Commun. 1999, 1883-
1884.
(5) Cameron, P. A.; Gibson, V. C.; Irvine, D. J . Angew. Chem. 2000,
112, 2225-2228; Angew. Chem., Int. Ed. 2000, 39, 2141-2144.
(6) Selected recent examples: (a) Mun˜oz-Hernandez, M. A.; Sanni-
grahi, B.; Atwood, D. A. J . Am. Chem. Soc. 1999, 121, 6747-6748. (b)
Radano, C. P.; Baker, G. L.; Smith, M. R. J . Am. Chem. Soc. 2000,
122, 1552-1553. (c) J hurry, D.; Bhaw-Luximon, A.; Spassky, N.
Macromol. Symp. 2001, 175, 67-79. (d) Ovitt, T. M.; Coates, G. W. J .
Am. Chem. Soc. 2002, 124, 1316-1326. (e) Nomura, N.; Ishii, R.;
Akakura, M.; Aoi, K. J . Am. Chem. Soc. 2002, 124, 5938-5939.
(7) (a) Lewin´ski, J .; Zachara, J .; Starowieyski, K. B. J . Chem. Soc.,
Dalton Trans. 1997, 4217-4222. (b) Lewin´ski, J .; Zachara, J .; Kopec´,
T.; Starowieyski, K. B.; Lipkowski, J .; J ustyniak, I.; Kołodziejczyk, E.
Eur. J . Inorg. Chem. 2001, 1123-1126. (c) Lewin´ski, J .; Zachara, J .;
J ustyniak, I. Organometallics 1997, 16, 4597-4605. (d) Lewin´ski, J .;
Zachara, J .; J ustyniak, I. Chem. Commun. 2002, 1586-1587. (e)
Lewin´ski, J .; Zachara, J .; Horeglad, P.; Glinka, D.; Lipkowski, J .;
J ustyniak, I. Inorg. Chem. 2001, 40, 6086-6087.
† Warsaw University of Technology.
‡ E-mail: lewin@ch.pw.edu.pl.
§ Polish Academy of Sciences.
(1) For a recent review see: Atwood, D. A.; Harvey, M. J . Chem.
Rev. 2001, 101, 37-52.
(2) For applications in asymmetric catalysis, see for example:
Canali, L.; Sherrington, D. C. Chem. Soc. Rev. 1999, 28, 85-93.
(3) For applications in olefin polymerization see: (a) Gibson, V. C.;
Spitzmesser, S. K. Chem. Rev. 2003, 103, 283-315. (b) Britovsek, G.
J . P.; Gibson, V. C.; Wass, D. F. Angew. Chem., Int. Ed. Engl. 1999,
38, 428-447.
(8) Branch, C. S.; Lewin´ski, J .; J ustyniak, I.; Bott, S. G.; Lipkowski,
J .; Barron, A. R. J . Chem. Soc., Dalton Trans. 2001, 1253-1258.
10.1021/om030331v CCC: $25.00 © 2003 American Chemical Society
Publication on Web 07/30/2003

3774 Organometallics, Vol. 22, No. 18, 2003
Lewin´ski et al.
model system for the study of the role of hydrogen
bonding on the structure of Schiff base metal complexes.
Additionally, our choice of target complexes was dictated
by the fact that the organometallic chemistry of group
13 elements with bidentate salicylideneiminate ligands
remains relatively poorly explored (for example, the
structurally characterized four-coordinated aluminum
complexes of this type include only sterically encum-
bered ligands,10,11 while complexes incorporating boron
and gallium have been rare12-14), and these studies are
in the course of our recent investigations toward volatile
main-group organometallic compounds as precursors for
MOCVD.15,16
Our previous studies on the solid-state and solution
properties of various group 13 chelate complexes have
revealed that minor differences in the subunit structure
can have a profound effect on the association of metal
alkoxides (aryloxides).7b,17 We have delineated factors
which provide a better understanding of the structural
and bonding parameters for the metal alkyl derivatives
of saturated and unsaturated donor-functionalized hy-
droxy compounds (L-H) upon moving from monomeric
four-coordinate R2M(η2-L) to five-coordinate [R2M(µ,η2-
L)]2 complexes or from four-coordinate [R2M(µ,η1-L)]2 to
five-coordinate [R2M(µ,η2-L)]2 adducts.7c,18,19 Very re-
cently, we have also reported results aiding our under-
standing of relationships between intra- and inter-
molecular forces resulting from donor-acceptor and hy-
drogen-bonding interactions using group 13 alkoxides
and carboxylates as model complexes.7b,9 In a continu-
ation of our systematic studies, we report here on
structure investigations of the group 13 organometallic
chelate complexes (M ) Al, Ga, In) with salicylidene-
iminate anion as the O,N-bidentate ligand. The influ-
ence of weak hydrogen bonds on the supramolecular
structure of resulting complexes is also discussed.
Resu lts a n d Discu ssion
Syn th esis a n d Solu tion Str u ctu r e. The reaction
of Me3M with 1 equiv of N-phenylsalicylideneimine
(saldPh-H) in toluene solution allows for the isolation
of the chelate complexes Me2M(saldPh) (where M ) Al
(1), Ga (2), In (3)) almost quantitatively. Each compound
was isolated as a yellow crystalline solid following
evaporation to dryness of the reaction mixture and
subsequent recrystallization from hexane/CH2Cl2 solu-
tion at 0 °C. The resulting compounds have been
characterized in a solution by NMR and IR spectroscopy
and cryoscopic molecular weight measurements. In the
solid state, the molecular structures of 1-3 have been
determined by X-ray diffraction techniques. The molec-
ular weight measurements have revealed that the
aluminum and gallium compounds 1 and 2 occur as
monomeric species in solution. Interestingly, a freshly
prepared benzene solution of the crystalline 2 consists
of some higher aggregated species, as judged from the
cryoscopic determination, likely the hydrogen-bonded
associates (vide infra). Initially, the degree of association
varied in the range of 1.2-1.3 and after ca. 1/2 h reached
a value of 1.0, corresponding to monomeric species (see
Experimental Section). In contrast, the indium com-
pound 3 occurs as a dimer in benzene solution. The
27Al NMR spectrum of 1 consists of a single resonance
at 149 ppm corresponding to a four-coordinate alumi-
num center. It is worth noting that the intensity of the
resonance signal is relatively low and a problem with
the detection of resonance signals presumably results
from the quadrupole moment of aluminum and nitrogen
(this aspect will be discussed in more details elsewhere).
(9) Lewin´ski, J .; J ustyniak, I.; Lipkowski, J .; Zachara, J . Inorg.
Chem. Commun. 2000, 3, 700-703.
(10) Cameron, P. A.; Gibson, V. C.; Redshaw, C.; Segal, J . A.; Solan,
G. A.; White, A. J . P.; Williams, D. J . J . Chem. Soc., Dalton Trans.
2001, 1472-1476.
(11) Hill, M. S.; Hutchison, A. R.; Keizer, T. S.; Parkin, S.; Van-
Aelstyn, M. A.; Atwood, D. A. J . Organomet. Chem. 2001, 628, 71-75.
(12) Mun˜oz-Hernandez, M. A.; Keizer, T. S.; Parkin, S.; Patrick, B.;
Atwood, D. A. Organometallics 2000, 19, 4416-4421.
(13) Shen, Y.-Z.; Gu, H.; Pan, Y.; Dong, G.; Wu, T.; J in, X.-P.; Huang,
X.-Y.; Hu, H. J . Organomet. Chem. 2000, 605, 234-238.
(14) (a) Allmann, R.; Hohaus, E.; Olejnik, S. Z. Naturforsch., B 1982,
37, 1450. (b) Hopfl, H.; Farfan, N. Can. J . Chem. 1998, 76, 1853. (c)
Kompan, O. E.; Furmanova, N. G.; Struchkov, Y. T.; Sitkina, L. M.;
Bren, V. A.; Minkin, V. I. Zh. Strukt. Khim. 1980, 21, 90. (d) Atwood,
D. A.; J egier, J . A.; Remington, M. P.; Rutherford, D. Aust. J . Chem.
1996, 49, 1333.
1
The H NMR spectra of 1-3 show no complexity, and
single resonances of the M-Me protons as well as the
NdCH proton and multiplets of aromatic protons are
observed. Thus, the above data are consistent with the
monomeric tetrahedral chelate structure I for the
aluminum and gallium derivatives and dimeric struc-
ture II for the indium complex.
(15) Starowieyski, K. B.; Chwojnowski, A.; J ankowski, K.; Lewin´ski,
J .; Zachara, J . Appl. Organomet. Chem. 2000, 14, 616-622. Starow-
ieyski, K. B.; Lewin´ski, J .; Woz´niak, R.; Lipkowski, J .; Chro´st, A.
Organometallics 2003, 22, 2458-2463.
(16) For recent studies on group 13 chelate complexes as precursors
for MOCVD see: (a) Park, J . H.; Horley, G. A.; O’Brien, P.; J ones, A.
C.; Motevalli, M. J . Mater. Chem. 2001, 11, 2346-2349. (b) Xu, C. Y.;
Baum, T. H.; Guzei, I.; Rheingold, A. L. Inorg. Chem. 2000, 39, 2008-
2010.
(17) Lewin´ski, J .; J ustyniak, I.; Ochal, Z.; Zachara, J . J . Chem. Soc.,
Dalton Trans. 1999, 2909-2911.
(18) Lewin´ski, J .; Zachara, J .; J ustyniak, I. Chem. Commun. 1997,
1519-1520.
(19) For selected examples of related works from other groups see:
(a) Schumann, H.; Girgsdies, F.; Dechert, S.; Gottfriedsen, J .; Hum-
mert, M.; Schutte, S.; Pickardt, J . Z. Anorg. Allg. Chem. 2002, 628,
2625-2630. (b) Schumann, H.; Wernik, S.; Wassermann, B. C.;
Girgsdies, F. J . Organomet. Chem. 2001, 621, 317-326. (c) Gelbrich,
T.; Hecht, E.; Thiele, K.-H.; Sieler, J . J . Organomet. Chem. 2000, 595,
21-30. (d) Lin, C.-H.; Ko, B.-T.; Wang, F.-C.; Lin, C.-C.; Kuo, C.-Y. J .
Organomet. Chem. 1999, 575, 67-75. (e) Francis, J . A.; McMahon, C.
N.; Bott, S. G.; Barron, A. R. Organometallics 1999, 18, 4399-4416.
(f) Francis, J . A.; Bott, S. G.; Barron, A. R. J . Chem. Soc., Dalton Trans.
1998, 3305-3310. (g) Hendershot, G.; Barber, M.; Kumar, R.; Oliver,
J . P. Organometallics 1991, 10, 3302-3309.
Liga n d Red istr ibu tion Rea ction s. We have previ-
ously reported that four-coordinate dialkylaluminum
complexes with a symmetrical bidentate acetylacetonate
ligand disproportionate in the presence of a Lewis base,
and the formation of stable five-coordinate adducts with
Lewis bases, i.e. R2Al(acac)(L), or bis-chelate RAl(acac)2
complexes (as an intermediate in the disproportionation
reaction) was not observed.20,21 We have been able to
isolate analogous five-coordinate aluminum complexes,
however, for unsymmetrical bidentate ligands such as
(20) Pasynkiewicz, S.; Lewin´ski, J . J . Organomet. Chem. 1985, 290,
15-23.

Group 13 Derivatives of N-Phenylsalicylideneimine
Organometallics, Vol. 22, No. 18, 2003 3775
methyl salicylate (mesalH) or 2′-aminoacetophenone
(amketH).22,23 As an extension of our studies on the
reactivity of group 13 chelate complexes toward nucleo-
philic reagents and ligand redistribution reactions we
have investigated the reaction of Me2M(saldPh) with
γ-picoline. The reaction of 1 with 1 equiv (or excess) of
γ-picoline in toluene solution at ambient temperature
resulted in a disproportionation reaction and the forma-
tion of the five-coordinate complex MeAl(saldPh)2 (4)
almost quantitatively. The 27Al NMR spectrum of 4
consists of a single resonance at 57 ppm corresponding
to the five-coordinate aluminum center.24 It is interest-
ing to note at this point that the chemical shift of 4 is
close to those observed for the related O,N-chelate
complex MeAl(amket)2 (67 ppm)23 and O,O′-chelate
complex MeAl(mesal)2 (66 ppm).24 Thus, for the RAl-
(O,N)2 complexes the chemical shifts fall in a relatively
narrow range, ∼10 ppm, despite the reverse position of
N and O substituents in the metal coordination sphere
(the equatorial vs axial position) or substitution of N-
for O-donor sites. These observations indicate that the
nature of a chelating ligand in the neutral five-
coordinated alkylaluminum bis-chelate complexes does
not affect substantially the aluminum nuclei shielding.
In contrast to the aluminum complex 1, the gallium and
indium analogues are stable in the presence of γ-pi-
coline, which clearly demonstrates that the latter
compounds are much less prone toward ligand redis-
tributions. There is also no detectable complexation of
F igu r e 1. ORTEP diagram of Me2Al(saldPh) (1). Thermal
ellipsoids are drawn at 50% probability.
1
γ-picoline by the metal center of 2 and 4 by H NMR
spectroscopy.
F igu r e 2. ORTEP diagram of Me2Ga(saldPh) (2). Thermal
ellipsoids are drawn at 50% probability.
Solid -Sta te Str u ctu r es of 1-4. The X-ray diffrac-
tion studies were carried out in order to determine the
degree of aggregation, the presence or absence of
intermolecular noncovalent interactions, and other per-
tinent structural details. Crystals of compounds 1-3
suitable for an X-ray structure determination were
grown from toluene/n-hexane solutions at -20 °C. The
solid structures of 1 and 2 are isostructural and
comprise monomeric species with the extended hydro-
gen bond network. Compound 3 is dimeric in the solid
state, with no unusually short intermolecular contacts.
Compounds 1 and 2 both crystallize in the tetragonal
space group I41/a as solvates with disordered molecules
of n-hexane. The molecular structures of 1 and 2 are
shown in Figures 1 and 2, respectively, while selected
interatomic distances and angles are collected in Table
1. Both compounds exist in the solid state as monomeric
four-coordinate chelate complexes. The chelate ligands
bind to the metal centers in an unsymmetrical fashion.
The Al(1)-O(1) and much longer Al(1)-N(1) distances
for 1 (1.7724(19) and 1.963(2) Å) are in accordance with
corresponding linkages in the simple four-coordinate
chelate analogues (Schiff base derivatives).
In compound 2 the Ga(1)-O(1) distance (1.889(3) Å)
is longer by about 0.12 Å than that found for 1.
However, the Ga-C bond lengths are the same as the
Al-C lengths. Taking into account the differences
between the covalent or ionic radii of aluminum (1.18,
0.53 Å) and gallium (1.26, 0.61 Å), one should state the
relative weakening of M-O and strengthening of M-C
bonds on going from aluminum to gallium: e.g., the
increase of covalent character of M-C bonds. It is
consistent with the increasing electronegativity of the
metal centers and indicates greater s-orbital character
in the Ga-C bonds. In both structures, the metal center
has a distorted-tetrahedral geometry with angles rang-
ing from 95.14(9) to 119.09(14)° and from 93.19(14) to
125.3(3)° in 1 and 2, respectively. The most acute angle
in each case is associated with the bite of the chelating
ligand. Consequently, the greater s-orbital character of
Ga-C bonds leads to a more obtuse C-Ga-C angle
(125.3(3)°) by comparison to the C-Al-C angle
(119.09(14)°). The same trend in widening of the C-M-C
angle has been observed for the dimeric five-coordinate
[R2M(O,O′)]2 -type complexes when passing from Al to
Ga and In derivatives (vide infra).7a The remaining bond
lengths and angles of the O,N-ligands in compounds 1
and 2 do not differ significantly. The six-membered
chelate rings in compounds 1 and 2 adopt a sofa
conformation. The Al and Ga atoms are displaced by
0.250(3) and 0.314(5) Å, respectively, out of the almost
flat ligand plane. We demonstrated recently that for
unsaturated bidentate ligands the strength of the
interaction between donor sites and the metal center is
significantly controlled by the conformation of the
(21) It is interesting to note that there has been one report on the
isolation and structure characterization of a five-coordinate dimeth-
ylgallium complex with a related symmetrical ligand, Me2Ga(hfac)(L)
(where hfac ) 1,1,1,5,5,5-hexafluoro-2,4-penatedionato and L ) pyri-
dine): Beachley, O. T., J r.; Gardinier, J . R.; Churchill, M. R.; Toomey,
L. M. Organometallics 1998, 17, 1101-1108.
(22) Lewin´ski, J .; Zachara, J .; Man´k, B.; Pasynkiewicz, S. J .
Organomet. Chem. 1993, 454, 5-7.
(23) Lewin´ski, J .; Zachara, J .; Kopec´, T.; Ochal, Z. Polyhedron 1997,
16, 1337-1341.
(24) Lewin´ski, J . In Encyclopedia of Spectroscopy and Spectrometry;
Lindon, J . C., Tranter, G. E., Holmes, J . L., Eds.; Academic Press: New
York, 1999; Vol. 1, pp 691-703.

3776 Organometallics, Vol. 22, No. 18, 2003
Lewin´ski et al.
Ta ble 1. Selected Bon d Len gth s (Å), Bon d An gles
(d eg), a n d Tor sion An gles (d eg) for Com p ou n d s
1-4
1‚1/4C6H14
2‚1/4C6H14
Al(1)-O(1)
Al(1)-N(1)
Al(1)-C(8)
Al(1)-C(9)
O(1)-C(1)
N(1)-C(7)
C(1)-C(2)
C(2)-C(7)
C(8)-Al(1)-C(9)
O(1)-Al(1)-N(1)
C(1)-O(1)-Al(1)
C(7)-N(1)-Al(1)
O(1)-C(1)-C(2)
C(1)-C(2)-C(7)
N(1)-C(7)-C(2)
1.7724(19) Ga(1)-O(1)
1.889(3)
2.023(3)
1.942(5)
1.940(5)
1.324(5)
1.288(5)
1.407(6)
1.432(6)
125.2(3)
93.21(14)
127.1(3)
122.1(3)
123.7(4)
123.7(4)
127.3(4)
1.963(2)
1.943(3)
1.946(3)
1.337(3)
1.296(3)
1.402(3)
1.434(3)
119.09(14) C(8)-Ga(1)-C(9)
95.14(9)
129.71(17) C(1)-O(1)-Ga(1)
121.68(18) C(7)-N(1)-Ga(1)
Ga(1)-N(1)
Ga(1)-C(8)
Ga(1)-C(9)
O(1)-C(1)
N(1)-C(7)
C(1)-C(2)
C(2)-C(7)
O(1)-Ga(1)-N(1)
121.6(2)
123.2(2)
126.5(3)
O(1)-C(1)-C(2)
C(1)-C(2)-C(7)
N(1)-C(7)-C(2)
Al(1)-O(1)-C(1)- -13.4(4)
C(2)
Ga(1)-O(1)-C(1)- -15.5(7)
C(2)
Al(1)-N(1)-C(7)- 0.7(4)
C(2)
Ga(1)-N(1)-C(7)- 1.9(7)
C(2)
3
4
In(1)-O(1)
In(1)-N(1)
In(1)-O(1′)
In(1)-C(8)
In(1)-C(9)
O(1)-C(1)
N(1)-C(7)
C(1)-C(2)
2.158(3)
2.366(3)
2.477(3)
2.137(5)
2.133(5)
1.331(5)
1.286(5)
1.409(6)
1.440(6)
140.3(2)
Al(1)-O(1)
Al(1)-O(2)
Al(1)-N(1)
Al(1)-N(2)
Al(1)-C(8)
O(1)-C(1)
1.7725(11)
1.7771(11)
2.1034(12)
2.1305(13)
1.9775(17)
1.3277(17)
1.3197(17)
1.2869(19)
1.2905(19)
118.49(6)
119.78(7)
121.72(7)
169.20(5)
88.92(5)
O(2)-C(21)
N(1)-C(7)
C(2)-C(7)
N(2)-C(27)
O(1)-Al(1)-O(2)
C(9)-In(1)-C(8)
C(9)-In(1)-O(1) 110.58(16) O(1)-Al(1)-C(8)
C(8)-In(1)-O(1) 108.29(17) O(2)-Al(1)-C(8)
O(1)-In(1)-N(1) 82.01(11) N(1)-Al(1)-N(2)
O(1)-In(1)-O(1′) 74.51(11) O(1)-Al(1)-N(1)
N(1)-In(1)-O(1′) 156.23(11) O(2)-Al(1)-N(2)
87.54(5)
133.70(10)
C(1)-O(1)-In(1) 133.2(3)
C(1)-O(1)-In(1′) 121.3(2)
C(7)-N(1)-In(1) 125.1(3)
In(1)-O(1)-In(1) 105.49(11) C(27)-N(2)-Al(1) 122.02(10)
In(1)-O(1)-C(1)- -4.8(6)
C(2)
C(1)-O(1)-Al(1)
C(21)-O(2)-Al(1) 134.48(9)
C(7)-N(1)-Al(1) 123.57(10)
F igu r e 3. (a, top) View of the helical chain structure of
Me2Al(saldPh) (1). (b, bottom) View of the crystal packing
in compound 1 along the c axis. The dashed lines and the
dotted lines represent C-H‚‚‚O and C-H‚‚‚π(Ph) hydrogen
bonds, respectively. Disordered n-hexane molecules are
each shown as a superposition of four sets of atomic
positions. Hydrogen atoms are omitted, excluding those
involved in H-bond formation.
Al(1)-O(1)-C(1)- 19.7(2)
C(2)
In(1)-N(1)-C(7)- -13.5(6)
Al(1)-O(2)-C(21)- -156.11(13)
C(2)
C(26)
chelate heterocyclic ring.25 Hence, it is reasonable to
assume that the conformation of the heterocyclic ring
in 1 and 2, in the absence of steric hindrances, results
from the intermolecular noncovalent forces.
respectively). Additionally, weaker interactions of the
C-H‚‚‚π(Ph) type between aromatic hydrogens and
ligand aromatic rings of adjacent molecules significantly
mediate the assembly. In both structures the inter-
molecular C-H‚‚‚π-centroid separations are equal, ∼3.03
Å, and lie in the accepted distance range for these types
of contacts.26 In crystals of 1 and 2 parallel alternating
left- and right-handed helical chains are thus further
joined by C-H‚‚‚π(Ph) interactions to form a tetragonal
net. In that case one could expect the formation of
channels surrounded by parallel helices. However,
examination of the space-filling model indicates only the
existence of oblate spheroidal cavities with dimensions
of ∼7.2 × 6.5 Å into which the guest molecules (n-
hexane) are included without any specific interaction
between guest and host. The resulting H-bonded 3D
frameworks with the disordered solvent molecules are
A detailed inspection of the crystal structures of
compounds 1 and 2 revealed that the weak intermo-
lecular hydrogen bond systems play a substantial role
in the molecular assembly of crystalline complexes. Most
interestingly, in both crystals adjacent monomeric
moieties are linked by the C-Himino‚‚‚O hydrogen bonds
(with the aryloxide oxygen acting as the hydrogen
acceptor) to form an infinite 1D helix running along the
c axis, as depicted in Figure 3a and Figure S1a (Sup-
porting Information) for 1 and 2, respectively. The
helical structures of 1 and 2 deserve special attention.
The helices are formed around crystallographic 41 and
43 screw axes, and each coil of the helix therefore
contains four residues. The distances between coils are
equal, ∼20.0 Å, and correspond to the unit cell param-
eter c (19.995(3) and 20.0042(13) Å for 1 and 2,
(26) Desiraju, G. R.; Steiner, T. The Weak Hydrogen Bond in
Structural Chemistry and Biology; IUCr Monographs on Crystal-
lography 9; Oxford University Press/International Union of Crystal-
lography: Oxford, U.K., 1999.
(25) Lewin´ski, J .; Gos´, P.; Kopec´, T.; Lipkowski, J .; Luboradzki, R.
Inorg. Chem. Commun. 1999, 2, 374-377.

Group 13 Derivatives of N-Phenylsalicylideneimine
Organometallics, Vol. 22, No. 18, 2003 3777
Ta ble 2. Selected In tr a - a n d In ter m olecu la r
Con ta cts (Å, d eg) in th e Str u ctu r es of 1, 2, a n d 4
C-H‚‚‚O
C-H
(Å)
H‚‚‚O
(Å)
C‚‚‚O
(Å)
C-H‚‚‚O
(deg)
compd
1
2
C(7)-H(7)‚‚‚O(1′)a
C(7)-H(7)‚‚‚O(1′)a
0.93
0.93
2.54
2.51
3.327(3) 143
3.302(5) 144
C(14)-H(14)‚‚‚O(1′)b 0.97(2) 2.60(2) 3.500(2) 153.9(16)
4
C(15)-H(15)‚‚‚O(2′)b 0.94(2) 2.61(2) 3.456(2) 148.8(15)
C(35)-H(35)‚‚‚O(1)
0.97(2) 2.52(2) 3.049(2) 114.2(15)
C-H‚‚‚π
C-H
(Å)
H‚‚‚Cg
C‚‚‚Cg
(Å)
C-H‚‚‚Cg
(deg)
(Å)d
1
2
C(4)-H(4)‚‚‚π(Ph′)c
C(4)-H(4)‚‚‚π(Ph′)c
0.93
0.93
3.03
3.03
3.789(4)
3.800(6)
140
142
a
3
b
Symmetry code /4 - y, 1/4 + x, 1/4 + z. Symmetry code 1 - x,
1 - y, -z. c Symmetry code -1/4 + y, 5/4 - x, 1/4 - z. Cg ) phenyl
ring centroid.
d
F igu r e 4. ORTEP diagram of [Me2In(saldPh)]2 (3). Ther-
mal ellipsoids are drawn at 50% probability. Hydrogen
atoms are omitted for clarity.
shown in Figure 3b and Figure S1b (Supporting Infor-
mation), and the shortest intermolecular C-H‚‚‚O and
C-H‚‚‚π contacts with distances and angles are sum-
marized in Table 2.
dimer consists of a nearly planar trans-6,6,4,6,6-fused
ring system with an rms deviation of atoms from the
mean plane equal to 0.075 Å.
The observed assembly mode of helices gives rise to
a noncovalent framework structure with the voids
volume of about 12% of the unit cell. Solvent-accessible
areas reside in special positions on the 4-fold inversion
axis 4h (4a position according to Wyckoff notation). The
4-fold rotation wraps the molecule around with the
metal-bonded methyl groups pointing outward. Due to
the weak host-guest interactions, the solvent molecules
are disordered. It is worth noting that the crystals of 1
and 2 are isostructural, which indicates that the nature
of the metal center does not affect the molecular
assembly of the tetrahedral aluminum and gallium
complexes derived from N-phenylsalicylideneimine. In-
terestingly, our analysis of intermolecular contacts in
the related structure of (N-methylsalicylideneiminato)-
dimethylgallium, [Me2Ga(saldMe)],27 shows that the
replacement of the N-phenyl with an N-methyl group
in the bidentate salicylideneiminate ligand leads to
significant changes in the molecular assembly of the
tetrahedral R2M(O,N) complex (the arrangement of
molecules in the crystal structure of Me2Ga(saldMe)
is determined, as in compounds 1 and 2, by the
C-Himino‚‚‚O interactions and result in the forma-
tion of infinite H-bonded chains assembled by weak
C-H‚‚‚π(Ph) interactions into the double layers without
guest molecules). However, this issue will be discussed
in detail together with our comprehensive analysis of
the hydrogen-bond supramolecular structures of group
13 metal Schiff base complexes based on the Cambridge
Structural Database.28
The overall molecular symmetry is crystallographi-
cally constrained to be centrosymmetric. Thus, the
central In2(µ-O)2 bridging ring is exactly planar with
internal angles (O(1)-In(1)-O(1′) ) 74.51(11)°) com-
parable to those reported for other oxygen-bridged five-
coordinate dialkylindium complexes of the type [R2In-
(O,X)]2 (where X ) O, N).7a,29,30 The geometry at the
indium atom can be described as distorted trigonal
bipyramidal, with carbon atoms C(8) and C(9) and
aryloxide oxygen O(1) occupying the equatorial sites.
The equatorial angles range from 108.3(2) to 140.3(2)°,
the latter being the angle between the methyl groups.
The widening of the C-In-C angle fits well with that
for other analogous five-coordinated dimeric chelate
[R2In(O,O′)]2 complexes, where these angles fall in the
range 135-155°, and it is consistent with the trend to
increase the C-M-C angle on going down group 13
(increasing s-orbital character of the M-C bonds).7a The
In(1) atom is significantly moved (0.110(3) Å) out of the
equatorial plane in the direction of the N(1) atom. The
axial positions are occupied by the imino nitrogen atom
N(1) and the aryloxide O(1′) atom of the second mono-
meric unit. The angle formed by the axial bonds, N(1)-
In(1)-O(1′), is equal to 156.23(11)°, and the difference
in comparison to the ideal value of 180° is caused by
constraints in both the central In2(µ-O)2 and the six-
membered InOCCCN rings. The observed trigonal-
bipyramidal distortion is typical for five-coordinate
indium derivatives [R2In(O,X)]2 with a six-membered
chelate ring, which was analyzed in our previous paper
in detail.7a The distances In(1)-O(1) and In(1′)-O(1)
(2.158(3) and 2.477(3) Å, respectively) within the central
four-membered In2(µ-O)2 ring in 3 differ significantly,
despite the fact that the bridging oxygen atoms are
bonded to the equivalent indium atoms. It is apparent
that this results from the geometry of dimeric five-
coordinated molecules, which dictates that each oxygen
In contrast to the four-coordinate hydrogen-bonded
polymeric structures of 1 and 2, the indium analogue 3
is dimeric with In2(µ-O)2 bridges (Figure 4). Compound
3 crystallizes in the monoclinic space group P21/n with
two molecules per unit cell. The crystal structure of 3
comprises individual five-coordinate dimeric molecules
with no unusually short intermolecular contacts. The
(27) Bregadze, V. I.; Furmanova, N. G.; Golubinskaya, L. M.;
Kompan, O. Y.; Struchkov, Y. T.; Bren, V. A.; Bren, Z. V.; Lyubarskaya,
A. E.; Minkin, V. I.; Sitkina, L. M. J . Organomet. Chem. 1980, 192,
1-15.
(28) Zachara, J .; Lewin´ski, J .; Dranka, M. To be submitted for
publication.
(29) Alcock, N. W.; Degnan, I. A.; Roe, S. M.; Wallbridge, M. G. H.
J . Organomet. Chem. 1991, 414, 285-293.
(30) Wu, X. S.; Pan, Y.; Sun, X. Z.; Zhu, Y. Chin. J . Struct. Chem.
1999, 18, 418.

3778 Organometallics, Vol. 22, No. 18, 2003
Lewin´ski et al.
atom is in the equatorial position of one indium atom
and in the axial position with respect to the second
atom. The six-membered metallacycle is almost planar,
the maximum deviation from planarity being 0.062(2)
Å for the N(1) atom. There are no notable intermolecular
contacts in the structure of 3, and the packing is
controlled by the vdW interactions.
It is worth noting that generally the group 13 metal
alkyl compounds, derived from the equimolar reaction
between R3M and unsaturated bifunctional organic
compounds, form four-coordinate chelate complexes in
solution and they are known to dimerize in the solid
state.7a,c Hence, the observed tendency of dialkylalumi-
num and dialkylgallium derivatives of bifunctional
salicylideneimine to form four-coordinate R2M(O,N)
chelate complexes in both the solid state and solution
indicates that bidentate Schiff bases act as strongly
coordinating chelate ligands. In this regard, bidentate
Schiff bases resemble the aforementioned symmetrical
acetylacetonate ligand as well as related â-diketonates.
For example, the crystal structure of Me2Al(bacac)
(where bacac ) 1-benzoylacetonato ligand) consists of
mononuclear tetrahedral molecules which are held
together entirely by very weak secondary bonds.31 It
seems likely that the molecular structures of 1 and 2
are controlled by the π-interaction of the aryloxide
oxygen lone pair with the salicylideneimine extended π
system, which substantially weakens the Lewis basicity
of the potentially bridging oxygen and simultaneously
strengthens the basicity of the chelating CdN group.
One may expect essentially an equal contribution of
conventional resonance structures III and IV in the
F igu r e 5. ORTEP diagram of MeAl(saldPh)2 (4). Thermal
ellipsoids are drawn at 50% probability. Hydrogen atoms
are omitted for clarity.
respectively. The imino nitrogen atoms of the chelating
ligands are located in axial positions, and the angle
formed by the axial bonds is equal to 169.20(5)°. The
central CAlO2N2 core exhibits an approximate C2 sym-
metry. Nevertheless, the remaining part of the complex
shows considerable deviation from this symmetry. The
equatorial Al-O bond lengths (Al(1)-O(1) ) 1.773(1)
Å and Al(1)-O(2) ) 1.777(1) Å) are quite short and
comparable to those observed in the four-coordinate
complex 1 or reported for simple five-coordinate com-
plexes of the type RAl(O,O)2, e.g. MeAl(mesal)2 (Al-O
) 1.773(2) Å).22 They are also shorter than the Al-O
bonds in monoalkylaluminum Salen derivatives, which
cover the distance range from 1.78 to 1.83 Å.28 Conse-
quently, the axial Al-N distances (Al(1)-N(1) ) 2.1034-
(12) Å, Al(1)-N(2) ) 2.1305(13) Å) are noticeably longer
then those found in Salen complexes (average Al-N
distance 2.035 Å; 2.013-2.068 Å).28 In addition, mono-
alkylaluminum chelate complexes derived from these
unsymmetrical compounds are, like complex 4, rela-
tively stable, in contrast to the analogous acetylacetone
derivative.20 Thus, in this case, the bidentate Schiff base
resembles unsymmetrical unsaturated â-hydroxy car-
bonyl compounds such as methyl salicylate and 2-ami-
noacethophenone. All the above observations lead to the
conclusion that salicylideneimines are electronically
very flexible ligand systems.
monomeric chelate R2M(O,N) complexes. On the other
hand, the observed dimeric structure for the analogous
indium derivative 3 is fully consistent with our earlier
reported conclusion concerning the Lewis acidity of the
group 13 metal centers in the four-coordinate com-
plexes.7a However, the analysis of the bond length
alteration for 3 shows that the population of both
resonance forms in this dimeric complex is similar to
those observed for monomeric complexes 1 and 2.
The monoalkylaluminum compound 4 crystallizes in
the triclinic space group P1h with two molecules per unit
cell. The molecular structure of 4 is shown in Figure 5,
and selected bond lengths and angles are given in Table
1. The geometry at aluminum is best described as
trigonal bipyramidal, with the aryloxy oxygen atoms
O(1) and O(2) and carbon atom C(8) occupying the
equatorial plane. The angles between bonds in this
plane are close to 120°, ranging between 118.49(6) and
121.72(7)°. The coordination of the chelate ligands to
the aluminum center results in the formation of two six-
membered rings displaying a sofa conformation. Thus,
the aluminum atom is perched at 0.346(2) and 0.451(2)
Å above the O(1)N(1) and O(2)N(2) chelate planes,
The analysis of short intra- and intermolecular con-
tacts in 4 does reveal C-Haryl‚‚‚O hydrogen-bonding
interactions between two adjacent molecules related by
the center of symmetry (Table 2, Figure 6). These
interactions organize molecules into H-bonded dimers
in the solid state. As may be seen from Figure 6, the
phenyl group bonded to the N(1) nitrogen atom is
oriented in such a way that a weak C-Haryl‚‚‚O hydro-
gen bonds are formed with both aryloxy oxygen atoms
of the neighboring molecule, related by a center of
symmetry. Furthermore, the O(1) oxygen atom is ad-
ditionally engaged in the intramolecular C-Haryl‚‚‚O
interactions. The salicylideneimine aromatic ring π
stacking (π-π distance of ∼3.41 Å) is an additional motif
(31) Lewin´ski, J .; Lipkowski, J .; J ustyniak, I. To be submitted for
publication.

Group 13 Derivatives of N-Phenylsalicylideneimine
Organometallics, Vol. 22, No. 18, 2003 3779
Me2Al(sa ld P h ) (1). A solution of N-(2-hydroxybenzylidene)-
aniline (0.51 g, 2.61 mmol) in toluene (5 mL) was cooled to
-78 °C, and Me3Al (0.25 cm3, 2.61 mmol) was added dropwise.
After the addition was completed, the reaction mixture was
warmed to room temperature and stirred for 0.5 h; then the
volatiles were removed in vacuo. Complex 1 was obtained as
yellow crystals after a recrystallization from hexane/CH2Cl2
solution at 0 °C. Cryoscopic molecular weight (benzene solu-
tion): formula weight calcd for C15H16AlNO 253.28, found 253.
Anal. Calcd for C15H16AlNO: C, 71.13; H, 6.37; N, 5.53.
1
Found: C, 71.32; H, 6.57; N, 5.42. H NMR (C6D6): δ -0.24
(s, 6H, Al-CH3), 6.49-7.12 (m, 9H, Ar H), 7.39 (s, 1H, CHd
N). 27Al NMR (C6D6): δ 144. IR (cm-1): 456 (m), 496 (w), 516
(m), 548 (m), 572 (m), 596 (w), 644 (m), 676 (s), 744 (m), 808
(s), 908 (s), 936 (s), 992 (m), 1004 (w), 1032 (m), 1080 (w), 1096
(w), 1128 (s), 1152 (s), 1188 (s), 1228 (m), 1248 (w), 1320 (s),
1344 (m), 1384 (s), 1420 (w), 1452 (s), 1472 (s), 1492 (s), 1528
(s), 1548 (s), 1592 (s), 1616 (s), 1696 (w), 1800 (w).
Me2Ga (sa ld P h ) (2). The reaction was carried out by using
the same procedure as described for 1, using N-(2-hydroxy-
benzylidene)aniline (0.49 g, 2.51 mmol) and Me3Ga (0.25 cm3,
2.51 mmol). Cryoscopic molecular weight (benzene solution):
formula weight calcd for C15H16GaNO 296.02, found 352 (299
after 4 h). Anal. Calcd for C15H16GaNO: C, 60.86; H, 5.45; N,
4.73. Found: C, 61.08; H, 5.63; N, 4.60. 1H NMR (C6D6): δ
0.08 (s, 6H, Al-CH3), 6.46-7.13 (m, 9H, Ar H), 7.59 (s, 1H,
CHdN). IR (cm-1) 448 (w), 504 (w), 512 (w), 544 (m), 588 (m),
612 (w), 656 (w), 796 (m), 860 (m), 892 (w 936 (w), 988 (w),
1004 (w), 1032 (w), 1080 (w), 1100 (w), 1128 (m), 1152 (s), 1184
(s), 1204 (w), 1224 (w), 1320 (m), 1348 (w), 1388 (m), 1448 (s),
1468 (s), 1488 (m), 1540 (s 1592 (s), 1616 (s).
F igu r e 6. Hydrogen-bonded dimer of MeAl(saldPh)2 (4)
in the solid state. The dashed lines represent intra- and
intermolecular C-H‚‚‚O hydrogen bonds. The atoms la-
beled with a prime (′) are at symmetry-equivalent positions
(1 - x, 1 - y, -z). Hydrogen atoms are omitted, excluding
those involved in H-bond formation.
Me2In (sa ld P h ) (3). The preparation was carried the same
as described for 1, using N-(2-hydroxybenzylidene)aniline (0.49
g, 2.50 mmol) and Me3In (0.40 g 2.50 mmol). Cryoscopic
molecular weight (benzene solution): formula weight calcd for
controlling the intermolecular arrangement, as is also
pointed out by dotted lines in Figure 6.
C
15H16InNO 341.11, found 675. Anal. Calcd for C15H16InNO:
C, 52.82; H, 4.73; N, 4.11. Found: C, 52.74; H, 4.79; N, 4.06.
1H NMR (C6D6): δ 0.27 (s, 6H, Al-CH3), 6.53-7.26 (m, 9H,
Ar H), 7.59 (s, 1H, CHdN). IR (cm-1) 444 (w), 488 (w), 532
(m), 576 (w), 596 (w), 848 (w), 856 (w), 896 (s), 928 (w), 988
(w), 1000 (w), 1028 (w), 1048 (w), 1080 (w), 1096 (w), 1128
(w), 1148 (m), 1172 (m), 1252 (s), 1276 (s), 1320 (m), 1348 (w),
1396 (m), 1420 (s), 1440 (s), 1464 (m), 1488 (m), 1536 (s), 1548
(m), 1592 (s), 1612 (s), 1700 (w).
Con clu sion
This report deals with the molecular and crystal
structures of group 13 complexes supported by N-
phenylsalicylideneimine. The results presented here
show that bidentate Schiff bases act as strongly coor-
dinating chelate ligands, and in this regard, they
resemble the symmetrical acetylacetonato ligand as well
as related â-diketonates. On the other hand, Schiff base
ligands are electronically more flexible ligand systems
than the latter ligands. Interestingly, the monomeric
dialkylaluminum chelate complexes R2Al(saldPh) are
more prone to ligand redistribution reactions than the
gallium and indium analogues. The X-ray crystal struc-
ture analysis indicates the C-Himino‚‚‚O, C-Haryl‚‚‚O,
and C-H‚‚‚π hydrogen bonds and π-π stacking as
major intermolecular forces determining supramolecu-
lar structures of the studied complexes.
MeAl(sa ld P h )2 (4). To a solution of 1 (0,43 g, 1.00 mmol)
in n-hexane (4 mL) was added 4-methylpyridine (0.097 g, 1.04
mmol) at room temperature. After the mixture was stirred for
5 min, the solvent and excess of 4-methylpyridine were
removed in vacuo. Complex 4 was obtained as yellow crystals
after recrystallization from n-hexane/CH2Cl2 solution at 0 °C.
Anal. Calcd for C27H23AlN2O2: C, 74.64; H, 5.34; N, 6.45.
1
Found: C, 74.56; H, 5.40; N, 6.42. H NMR (C6D6): δ -0.25
(s, 3H, Al-CH3), 6.5-7.2 (m, 18H, Ar H), 7.40 (s, 2H, CHdN).
27Al NMR (C6D6): δ 57.
Cr ysta llogr a p h ic Stu d ies. Single crystals of 1-4 suitable
for X-ray diffraction studies were placed in thin-walled capil-
lary tubes (Lindemann glass) under an inert atmosphere,
which were then plugged with grease and flame-sealed. X-ray
diffraction data for compounds 1‚1/4C6H14 and 4 were collected
at room temperature on a Siemens P3 diffractometer and for
compounds 2‚1/4C6H14 and 3 on a Kuma KM4 diffractometer
equipped with a CCD detector. Crystal data and data collection
and refinement parameters for all compounds are given in
Table 3. The data sets were corrected for Lorentz-polarization
effects. A numerical absorption correction based on a well-
defined crystal shape was performed for compound 3. In the
case of 2‚1/4C6H14, an empirical correction based on multiple
scanned reflections was applied using the method published
by Blessing32 and implemented in the Platon package.33 The
Exp er im en ta l Section
All operations were carried out under dry nitrogen using
standard Schlenk techniques. Solvents and reagents were
purified and dried by standard techniques. NMR spectra were
recorded on a Varian Mercury (400 MHz) spectrometer in C6D6
solutions. The IR spectra were recorded on a Specord M80
spectrophotometer. Molecular weight determinations were
carried out cryoscopically in benzene solution. Elemental
analyses and molecular weight measurements were preceded
by the crystals crumbling and being maintained under high
vacuum for 3 h.
(32) Blessing, B. Acta Crystallogr., Sect. A 1995, 51, 33-38.

3780 Organometallics, Vol. 22, No. 18, 2003
Lewin´ski et al.
Ta ble 3. Cr ysta l Da ta , Da ta Collection , Str u ctu r e Solu tion , a n d Refin em en t P a r a m eter s for Com p ou n d s
1-4
1‚1/4C6H14
2‚1/4C6H14
3
4
formula
fw
C
15H16AlNO‚1/4C6H14
C
15H16GaNO‚1/4C6H14
C
30H32In2N2O2
C
27H23AlN2O2
274.81
317.55
682.22
434.45
cryst size, mm
cryst syst
space group, No.
temp, K
a, Å
0.34 × 0.16 × 0.16
tetragonal
I41/a, 88
293(2)
17.8274(17)
17.8274(17)
19.995(3)
90
0.30 × 0.20 × 0.20
tetragonal
I41/a, 88
293(2)
17.8866(19)
17.8866(19)
20.0042(13)
90
0.45 × 0.35 × 0.22
monoclinic
P21/n, 14
293(2)
9.0500(12)
9.2007(12)
17.7040(18)
90
105.303(10)
90
1421.9(3)
2
0.42 × 0.32 × 0.20
triclinic
P1h, 2
293(2)
9.7947(14)
10.6809(18)
12.4988(19)
68.886(12)
67.907(11)
79.741(12)
1128.9(3)
2
b, Å
c, Å
R, deg
â, deg
90
90
90
90
γ, deg
V, Å3
6354.7(13)
16
1.149
6400.0(10)
16
1.318
Z
D
calcd, g cm-3
1.593
1.278
F(000)
2344
2632
680
456
radiation used
Mo KR (λ ) 0.710 73 Å)
µ, mm-1
0.122
2.3-25.0
4585
2807, 0.0344
1371
2807/235/54
0.0474, 0.0909
0.0505, 0
+0.13, -0.15
1.714
1.650
0.117
θ range, deg
3.3-22.5
41 204
2086, 0.1180
1853
2086/225/54
0.0566, 0.0888
0.0321, 4.20
+0.26, -0.20
3.3-25.0
21 982
2.0-25.0
4256
no. of rflns collected
no. of unique data, Rint
no. of obsd data (I > 2σ(I))
no. of data/params/restraints
R1, wR2a
2491, 0.0585
2217
4000, 0.0105
3405
2491/168/0
0.0363, 0.0695
0.0127, 3.593
+1.45, -0.57
4000/382/0
0.0317, 0.0856
0.0487, 0.174
+0.20, -0.18
weights a, bb
largest resids, e Å-3
R1 ) ∑||Fo| - |Fc||/∑|Fo|; wR2 ) [∑w(Fo - Fc2)2/∑w(Fo4)]1/2
.
w ) 1/[σ2(Fo2) + (aP)2 + bP], where P ) (Fo + 2Fc2)/3.
a
2
b
2
and thermal parameters on adjacent atoms were restrained
to be similar. In all cases, the final Fourier difference maps
have no significant chemical meaning. ORTEP drawings were
made using Ortep3 for Windows.36
structures were solved by direct methods using the Shelxs-86
program.34 Full-matrix least-squares refinement against F2
values was carried out by using Shelxl-97.35 All non-hydrogen
atoms, except for the disordered solvent molecule in 2‚1/4C6H14
,
were refined with anisotropic displacement parameters. The
hydrogen atoms in the structure of compound 4 were located
from difference maps, and their positional and isotropic
thermal parameters were refined. For the remaining struc-
tures the hydrogen atoms were introduced at geometrically
idealized coordinates and allowed to ride on their parent C
atoms. Moreover, methyl hydrogen atoms in 1-3 were refined
as disordered groups with two positions rotated by 60° about
the M-C bond. The crystal solvents in 1‚1/4C6H14 and
2‚1/4C6H14 surrounded the special positions (4a) with 4h site
symmetry and were refined disordered with the sof fixed at
1/4. To assist in the refinement process, all C-C bonds in
disordered molecules of n-hexane were restrained to be equal,
Ack n ow led gm en t. This work was supported by the
State Committee for Scientific Research, Grant Nos. 3
T09A 066 19 and PBZ-KBN 15/T09/99/03. We are
indebted to Prof. K. Woz´niak from the Crystallographic
Unit of the Chemistry Department (University of War-
saw) for the X-ray measurements.
Su p p or tin g In for m a tion Ava ila ble: Complete tables of
atomic coordinates and anisotropic thermal parameters for all
non-hydrogen atoms, hydrogen positional and isotropic dis-
placement parameters, and interatomic distances and angles
for 1-4 and a crystal packing diagram for 2 (Figure S1). This
material is available free of charge via the Internet at
http://pubs.acs.org.
(33) (a) Spek, A. L. PLATON, A Multipurpose Crystallographic Tool;
Utrecht University, Utrecht, The Netherlands, 2002. (b) Spek, A. L.
Acta Crystallogr., Sect. A 1990, 46, C-34.
(34) Sheldrick, G. M. Acta Crystallogr., Sect. A 1990, 46, 467-473.
(35) Sheldrick, G. M. SHELXL-97, Program for Crystal Structure
Refinement; University of Go¨ttingen, Go¨ttingen, Germany, 1997.
OM030331V
(36) Farrugia, L. J . J . Appl. Crystallogr. 1997, 30, 565.