THE PREPARATION OF CYCLOHEXANEPENTOLS FROM INOSITOLS BY DEOXYGENATION

DOI: 10.1016/S0008-6215(00)81001-0

Source and publish data:

Carbohydrate Research p. 209 - 220 (1982)

Update date:2022-08-05

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Authors:

Angyal, Stephen J.

Odier, Leon

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Article abstract of DOI:10.1016/S0008-6215(00)81001-0

Several cyclohexapenetols heva been synthesized from inositols by blocking all but one hydroxyl group, converting the free hydroxyl group into its S-methyl dithiocarbonate, and treating it with tributylstannane.Suitable blocking-groups are methyl, benzyl, and methylthiomethyl ethers, and acetals.One cyclohexanepentol was prepared by the reductive deamination of an aminodeoxyinositol.

Full text of DOI:10.1016/S0008-6215(00)81001-0

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