Simple synthesis of oligosilyl-α,ω-dipotassium compounds

DOI: 10.1002/1521-3773(20020315)41:6<989::AID-ANIE989>3.0.CO;2-A

Source and publish data:

Angewandte Chemie - International Edition p. 989 - 992 (2002)

Update date:2022-08-02

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Authors:

Kayser, Christian

Kickelbick, Guido

Marschner, Christoph

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Article abstract of DOI:10.1002/1521-3773(20020315)41:6<989::AID-ANIE989>3.0.CO;2-A

Multiply metalated oligosilanes: Treatment of bridged bis[tris(trimethylsilyl)silyl] compounds with two equivalents of potassium tert-butoxide leads to the formation of 1,3- and 1,4-dipotassium silanes [Eq. (1)]. Reaction of the latter with zirconocene di

Full text of DOI:10.1002/1521-3773(20020315)41:6<989::AID-ANIE989>3.0.CO;2-A

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