Bulletin of the Chemical Society of Japan p. 2933 - 2937 (1980)
Update date:2022-09-26
Topics:
Yabe, Akira
It was found that the unexpected phenazines were formed as minor products by the low-temperature photolysis of 2,2'-diazidobiphenyls in a rigid matrix.The phenazine formation results from the 1,1-C-C bond fission of the biphenyl nucleus and suggests the aziridine intermediates.The low-temperature photolysis of 2-azido-2'-methylbiphenyl and 2-azido-2',4',6'-trimethylbiphenyl leads to the triplet-derived phenanthridine derivatives as major products.
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