Cyclic β-diketones - Precursors of chiral 1,3-cyclohexadiene iron carbonyl complexes. Ligand exchange -( -) -PPh2( O-HC * ( Me) -COOEt) - New, chiral, diastereomer-separating ligand in organoiron chemistry

DOI: 10.1016/0022-328X(95)05761-D

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Journal of Organometallic Chemistry p. 23 - 29 (1996)

Update date:2022-08-04

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Authors:

Bohac, Andrej

Lettrichova, Martina

Hrnciar, Pavel

Hutta, Milan

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Article abstract of DOI:10.1016/0022-328X(95)05761-D

A synthesis of new, chiral tricarbonyliron complexes (1,2) from 1,3-cyclohexanedione and 5,5-dimethyl-1,3-cyclohexanedione (dimedone) after their conversion to 1,3-diacetoxy-1,3-cyclohexadienes and complexation with Fe₂(CO)₉ is descr

Full text of DOI:10.1016/0022-328X(95)05761-D

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