Journal of Organic Chemistry p. 389 - 398 (1982)
Update date:2022-08-04
Topics:
Parker, Kathlyn A.
Petraitis, Joseph J.
Kosley, Raymond W.
Buchwald, Stephen L.
The reaction of a propargyl alcohol with an amide acetal affords enamine products, an allenic amide (a sigmatropic rearrangement product), or a product resulting from enamine formation followed by sigmatropic rearrangement.Subsequent procedures afforded α,β-unsaturated aldehydes, α-hydroxy ketones, β-keto amides, and spiro lactones.
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