Journal of the Chemical Society, Dalton Transactions p. 1164 - 1168 (1980)
Update date:2022-08-04
Topics:
Huggett, Paul G.
Lynch, Roderick J.
Waddington, Thomas C.
Wade, Kenneth
The 35Cl n.q.r. spectra of a series of tin(IV) chloride adducts SnCl4*2L A trans structure is indicated for SnCl4*2tht, cis structures for the remainder.When compared with other published n.q.r. and structural data, our results indicate that the 35Cl n.q.r. frequencies are related to the Sn-Cl bond lengths in such systems.The higher 35Cl n.q.r. frequencies tend to be associated with the shorter bonds, though the frequencies also vary markedly with temperature.
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