Proton-Transfer Reactions. 3. Differences in the Protonation of Localized and Delocalized Carbanion Intermediates

DOI: 10.1021/ja00346a047

Source and publish data:

Journal of the American Chemical Society p. 2388 - 2393 (1983)

Update date:2022-09-26

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Authors:

Koch, Heinz F.

Koch, Judith G.

Koch, Nanci H,

Koch, Andrew S.

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Article abstract of DOI:10.1021/ja00346a047

Rates, activation parameters, and product distributions are reported for the reaction of methanolic sodium methoxide with XC6H4CH = CF2 (V) and C6F5CH = CF2 (IX) and compared to previously reported results for C6H5C(CF3) = CF2 (I).A ρ = 3.5 was calculated

Full text of DOI:10.1021/ja00346a047

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