
Journal of Organic Chemistry p. 2228 - 2235 (1992)
Update date:2022-08-05
Topics:
Burke, Steven D.
Pacofsky, Gregory J.
Piscopio, Anthony D.
Syntheses of the trio of related mold metabolites ethisolide (1), isoavenaciolide (2), and avenaciolide (3) in racemic and optically active forms are described.Glycolate Claisen rearrangements governed by chelation control of enolate geometry and diastere
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