Diaryltellurium(IV) carboxylates: Synthesis via telluroxides and their characterization

Article abstract of DOI:10.1080/10426500008076544

The synthesis of some new diaryltellurium(IV) dicarboxylates (salicylate, benzoate, cinnamate) and carboxylales (oxalate, o-phthalate, succinate) by the reactions of bis(p-methoxyphenyl)telluroxide and bis(p-hydroxyphenyl)telluroxide with the corresponding carboxylic acid is reported. The resulting carboxylates have been subjected to elemental analyses, conductance and cryoscopic measurements, infra-red and proton magnetic resonance spectral studies. Solution studies reflect the non-ionic nature of these compounds. Infra-red spectral studies predict the unidentate nature of salicylate, benzoate and cinnamate and bidentate nature of oxalate, o-phthalate and succinate groups. A PMR spectral study confirms their proposed stoichiometry. These compounds possess a trigonal bipyramidal structure with a tetra-coordinate central tellurium atom.

Full text of DOI:10.1080/10426500008076544

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Phosphorus, Sulfur, and
Silicon and the Related
Elements
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DIARYLTELLURIUM(IV)
CARBOXYLATES: SYNTHESIS
VIA TELLUROXIDES AND
THEIR CHARACTERIZATION
K. K. Verma a , Daya Soni a & Sunil Verma a
a Department of Chemistry, M.D. University,
Rohtak, 124001, INDIA
Version of record first published: 19 Dec 2006.
To cite this article: K. K. Verma , Daya Soni & Sunil Verma (2000):
DIARYLTELLURIUM(IV) CARBOXYLATES: SYNTHESIS VIA TELLUROXIDES AND THEIR
CHARACTERIZATION, Phosphorus, Sulfur, and Silicon and the Related Elements,
166:1, 231-241
To link to this article: http://dx.doi.org/10.1080/10426500008076544
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