Organic Letters p. 3859 - 3862 (2003)
Update date:2022-09-26
Topics:
Andrus, Merritt B.
Hicken, Erik J.
Meredith, Erik L.
Simmons, Bryon L.
Cannon, John F.
(Matrix presented) The quinone portion of the ansamycin geldanamycin was made with complete selectivity from the 1,4-dihydroquinone generated from a 1,4-bis-methoxymethyl (MOM) ether intermediate. Palladium catalysis with air gave the desired product in 9
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