Journal of Organometallic Chemistry p. 39 - 56 (1988)
Update date:2022-07-30
Topics:
Voronkov, M. G.
Baryshok, V. P.
Petukhov, L. P.
Rakhlin, V. I.
Mirskov, R. G.
Pestunovich, V. A.
The electronic structure of 1-halosilatranes is discussed.Some new preparative methods based on hetero- and homo-lytic reactions of the silatrane and the Si- and C-substituted silatranes with halogenating reagents are described and also synthetic routes to 1-halosilatranes from certain organotrialkoxy- and organotrichlorosilanes.The electrophilic reactions of 1-iodosilatrane with ethers and esters, carbonyl compounds, alkoxysilanes and siloxanes, terminal alkynes and organomercurials have been studied
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