Tetrahedron Letters p. 1209 - 1212 (1985)
Update date:2022-08-05
Topics:
Bertrand, M. P.
Oumar-Mahamat, H.
Surzur, J. M.
Ag (I) mediated persulphate oxidation of various 2-methyl benzoic acids and acrylic acids, co-catalysed by Cu (II), leads to unsaturated γ-lactones, together with decarboxylation products.Lactonisation proceeds through 1,5 hydrogen trasfer from intermediate acyloxyl radicals.
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