ASYMMETRIC SYNTHESIS OF β-HYDROXY-α-ALKYLAMINO ACIDS BY ASYMMETRIC ALDOL REACTION OF α-ISOCYANOCARBOXYLATES CATALYZED BY CHIRAL FERROCENYLPHOSPHINE-GOLD(I) COMPLEXES

DOI: 10.1016/S0040-4020(01)86034-8

Source and publish data:

Tetrahedron p. 5253 - 5262 (1988)

Update date:2022-08-04

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Authors:

Ito, Yoshihiko

Sawamura, Masaya

Shirakawa, Eiji

Hayashizaki, Keiichi

Hayashi, Tamio

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Article abstract of DOI:10.1016/S0040-4020(01)86034-8

Aldol reaction of methyl α-isocyanocarboxylates (CNCH(R)COOMe: R = H, Me, Et, i-Pr) with benzaldehyde or acetaldehyde in the presence of 0.5-1.0 molpercent of a chiral (aminoalkyl)ferrocenylphosphine-gold(I) complex gave optically active 4-methoxycarbonyl

Full text of DOI:10.1016/S0040-4020(01)86034-8

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