FORMATION OF Fe3(NCMe)(CO)9 DURING THE REACTION OF Fe3(μ3-CMe)(CO)10X CLUSTERS WITH ALKYNES (X = NO) OR DIAZOALKANES (X = H). FIRST EXAMPLES OF ETHYLIDYNE-NITROGEN COUPLING TO ACETONITRILE

DOI: 10.1016/0022-328X(86)80186-3

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Journal of Organometallic Chemistry p. C5 - C6 (1986)

Update date:2022-08-04

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Authors:

Nuel, Didier

Mathieu, Rene

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Article abstract of DOI:10.1016/0022-328X(86)80186-3

Reaction of the clusters Fe3(μ₃-CCH3)(CO)10X with alkynes (X = NO) or diazoalkanes (X = H) lead among other products to the cluster Fe3(CH3CN)-(CO)9 in yields varying from 1 to 18percent, the acetonitrile ligand resulting from the coupling of t

Full text of DOI:10.1016/0022-328X(86)80186-3

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