Tetrahedron Letters p. 6485 - 6488 (1993)
Update date:2022-08-05
Topics:
Vidari, Giovanni
Dapiaggi, Antonella
Zanoni, Giuseppe
Garlaschelli, Luigi
The asymmetric dihydroxylation of geranyl acetate, neryl acetate and trans, trans-farnesyl acetate was studied using the new Sharpless' ligands (DHQD)2-PHAL and (DHQ)2-PHAL. High enantioselectivity was always observed. High positional selectivity for the 6,7-olefin was observed in the case of the monoterpene acetates.
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