Synlett p. 689 - 690 (1997)
Update date:2022-08-04
Topics:
Ouellet
Langlois
Deslongchamps, Pierre
Macrocyclic TCC triene 1, generated by an intramolecular alkylation of a β-ketoester on a π-allylpalladium complex followed by dehydrogenation, underwent a highly stereoselective transannular Diels-Alder reaction affording the tetracyclic compound 2 in an excellent yield.
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