Synthesis of a 14β-Hydroxysteroid Using the Transannular Diels-Alder Strategy

DOI: 10.1055/s-1997-3255

Source and publish data:

Synlett p. 689 - 690 (1997)

Update date:2022-08-04

Topics:

Authors:

Ouellet Ouellet

Langlois

Deslongchamps, Pierre

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Article abstract of DOI:10.1055/s-1997-3255

Macrocyclic TCC triene 1, generated by an intramolecular alkylation of a β-ketoester on a π-allylpalladium complex followed by dehydrogenation, underwent a highly stereoselective transannular Diels-Alder reaction affording the tetracyclic compound 2 in an excellent yield.

Full text of DOI:10.1055/s-1997-3255

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