ENHANCED REACTIVITY OF AN α-NUCLEOPHILE IN WATER-DIMETHYL SULFOXIDE MIXTURES. A TRANSITION STATE EFFECT.

DOI: 10.1016/S0040-4039(01)80130-1

Source and publish data:

Tetrahedron Letters p. 1267 - 1268 (1984)

Update date:2022-07-29

Topics:

Authors:

Laloi-Diard, Marguerite

Verchere, Jean-Francois

Gosselin, Patrick

Terrier, Francois

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Article abstract of DOI:10.1016/S0040-4039(01)80130-1

The reactivity of the anion of α,α,α-trifluoroacetophenone oxime towards p-nitrophenylacetate is considerably enhanced relative to that of the similarly basic p-chlorophenoxide anion on addition of Me2SO to aqueous solutions.This is shown to be due to an

Full text of DOI:10.1016/S0040-4039(01)80130-1

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