Reactions of (1-Chlorovinyl)diphenylphosphine Oxide with Organometallic Reagents

Article abstract of DOI:10.1016/S0040-4039(00)93399-9

Direct substitution of 1-chlorovinyl group by an aryl or an alkyl group in the reactions of (1-chlorovinyl)diphenylphosphine oxide with aryl and alkyl Grignard reagents was observed, whereas in its reactions with the corresponding cuprates addition across the double bond constituted the dominant reaction pathway.