Highly Regio- and Stereospecific Palladium-Catalyzed Allylation of Enolates Derived from Ketones

DOI: 10.1021/jo00137a038

Source and publish data:

Journal of Organic Chemistry p. 3188 - 3190 (1982)

Update date:2022-08-05

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Authors:

Negishi, Ei-ichi

Matsushita, Hajime

Chatterjee, Sugata

John, Robert A.

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Article abstract of DOI:10.1021/jo00137a038

The reaction of potassium enoxyborates, readily obtainable by treating potassium enolates with a trialkylborane, e.g., triethylborane, with allylic electrophiles such as allylic chlorides and acetates in the presence of a catalytic amount of a palladium-p

Full text of DOI:10.1021/jo00137a038

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