Angewandte Chemie - International Edition p. 4637 - 4640 (2013)
Update date:2022-08-05
Topics:
Han, Xinping
Wu, Jimmy
Secondary role: Indole and pyrrole derivatives are alkylated with unactivated secondary aliphatic alcohols by a Bronsted acid-catalyzed redox chain reaction mechanism. Broad functional-group tolerance has been demonstrated and preliminary studies suggest that 1,4-reduction of a putative indolyl carbocation is the dominant mechanistic pathway. Copyright
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