Synthesis of beta-substituted cyclopentenones via carbon alkylation of metalated gamma-methoxycyclopentenyl phenylsulfonyl anion

DOI: 10.1016/0040-4039(95)00822-T

Source and publish data:

Tetrahedron Letters p. 4537 - 4538 (1995)

Update date:2022-08-05

Topics:

Authors:

Kim, Seong Heon

Jin, Zhendong

Fuchs Fuchs

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(95)00822-T

Metalation of γ-methoxyallyl sulfone 13 provides phenylsulfonyl anion 2a which undergoes alkylation followed by hydrolysis to afford β-substituted cyclopentenones.

Full text of DOI:10.1016/0040-4039(95)00822-T

Products guided by the article

Product name:6-Oxabicyclo[3.1.0]hexane, 2-(phenylsulfonyl)-

Cas No:65825-68-5

R&D Labs maybe for 65825-68-5

Anhui Dexinjia Biopharm Co., Ltd

Contact:+86-531-82375818

Address:9 Hexie Road, kaifaqu, Taihe
Ceresking Ecology & Technology co.,ltd

Contact:86 22 66218397

Address:Room 1613, Zheshang Mansion, No. 1988, Yingbin Avenue, Binhai New District, Tianjin,China.
Anhui Dexinjia Biopharm Co., Ltd

Contact:+86-531-82375818

Address:9 Hexie Road, kaifaqu, Taihe
Tianjin Dongchang Fine Chemical Industry Co., Ltd.

Contact:+86-22-29894595

Address:Economic Developing Zone, Ji County, Tianjin, China
Mascot I.E. Co., Ltd.

website:http://www.mascot-ie.com

Contact:86-519-85010339

Address:B-802,XingBei Building,391#,Tongjiang Middle Road New District,Changzhou,JS,China

Relevant to this article

Preparation and biological assessment of hydroxycinnamic acid amides of polyamines

Doi:10.1016/S0031-9422(03)00133-X
(2003)
Chiral bases as useful probes of lithium amide reactivity

Doi:10.1002/anie.201206558
(2012)
Synthesis of the four possible stereoisomers of N-2′-methylbutyl-2-Methylbutylamide, the sex pheromone of the longhorn beetle Migdolus fryanus westwood

Doi:10.1081/SCC-100107019
(2001)
Doi:10.1055/s-1978-24681
(1978)
Transformation of β-chalcogeno alkenylboranes into tetrasubstituted olefins

Doi:10.1016/j.tet.2003.11.023
(2004)
Continuous multiple liquid-liquid separation: Diazotization of amino acids in flow

Doi:10.1021/ol301930h
(2012)

Article Doi