Synthesis of beta-substituted cyclopentenones via carbon alkylation of metalated gamma-methoxycyclopentenyl phenylsulfonyl anion

DOI: 10.1016/0040-4039(95)00822-T

Source and publish data:

Tetrahedron Letters p. 4537 - 4538 (1995)

Update date:2022-08-05

Topics:

Authors:

Kim, Seong Heon

Jin, Zhendong

Fuchs Fuchs

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(95)00822-T

Metalation of γ-methoxyallyl sulfone 13 provides phenylsulfonyl anion 2a which undergoes alkylation followed by hydrolysis to afford β-substituted cyclopentenones.

Full text of DOI:10.1016/0040-4039(95)00822-T

Products guided by the article

Product name:6-Oxabicyclo[3.1.0]hexane, 2-(phenylsulfonyl)-

Cas No:65825-68-5

R&D Labs maybe for 65825-68-5

Zhushan County Tianxin Pharmaceutical & Chemical Co., Ltd.

Contact:0086-719-4224892

Address:Tutang Road, Chengguan Town, Zhushan County, Hubei Province
Zouping Mingxing Chemical Co.,Ltd.

website:http://www.zoutong.com.cn

Contact:86-543-2240068 2240067

Address:428 Daixi Third Road Zouping County Shandong Province China
Shandong Topscience Biotech Co., Ltd.

Contact:0633-2619278

Address:No. 98 Lanshan West Road, Lanshan District, Rizhao, Shandong Province, P.R. of China
Suzhou Health Chemicals Co., Ltd.

website:http://www.healthchems.com

Contact:13776257979

Address:No. 338, Jingang Avenue,
Shifang Taifeng New Flame Retardant Co., Ltd

Contact:02884721008

Address:tingjiang industrial park, hefeng town

Relevant to this article

Preparation and biological assessment of hydroxycinnamic acid amides of polyamines

Doi:10.1016/S0031-9422(03)00133-X
(2003)
Chiral bases as useful probes of lithium amide reactivity

Doi:10.1002/anie.201206558
(2012)
Synthesis of the four possible stereoisomers of N-2′-methylbutyl-2-Methylbutylamide, the sex pheromone of the longhorn beetle Migdolus fryanus westwood

Doi:10.1081/SCC-100107019
(2001)
Doi:10.1055/s-1978-24681
(1978)
Transformation of β-chalcogeno alkenylboranes into tetrasubstituted olefins

Doi:10.1016/j.tet.2003.11.023
(2004)
Continuous multiple liquid-liquid separation: Diazotization of amino acids in flow

Doi:10.1021/ol301930h
(2012)

Article Doi