Highly reduced organometallics XXVII. Synthesis, isolation and characterization of trisodium tricarbonylcobaltate(3-), and initial studies on its derivative chemistry

DOI: 10.1016/0022-328X(90)85151-N

Source and publish data:

Journal of Organometallic Chemistry p. 521 - 530 (1990)

Update date:2022-07-29

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Authors:

Ellis, John E.

Barger, Paul T.

Winzenburg, Mark L.

Warnock, Garry F.

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Article abstract of DOI:10.1016/0022-328X(90)85151-N

Reduction of A by three equivalents of A (A = sodium or potassium) in liquid ammonia provides salts containing tricarbonylcobaltate(3-).A satisfactorily pure sodium compound, Na3 is described for the first time.Reactions of A3 w

Full text of DOI:10.1016/0022-328X(90)85151-N

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