Efficient Preparation of Some Biologically Active Substances from Natural and Nonnatural Aromatic Compounds by m-Chloroperbenzoic Acid Oxidation

DOI: 10.1021/jo00258a010

Source and publish data:

Journal of Organic Chemistry p. 5453 - 5457 (1988)

Update date:2022-08-04

Topics:

Authors:

Asakawa, Yoshinori

Matsuda, Reiko

Tori, Motoo

Sono, Masakazu

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00258a010

Six naturally occurring aromatic terpenoids and six nonnatural aromatic compounds were oxidized by m-chloroperbenzoic acid in chloroform to give 1,2- and 1,4-quinones or hydroxylated products in which vitamin K₁, insecticidal, piscicidal, and antifungal compounds were included.The present method is advantageous for obtaining different types of natural or nonnatural aromatic products having biological activity from the starting aromatic compounds in a one-step reaction.

Full text of DOI:10.1021/jo00258a010

Products guided by the article

Product name:2,5-Cyclohexadiene-1,4-dione, 2-methyl-5-(1,2,2-trimethylcyclopentyl)-, (R)-

Cas No:66389-31-9

R&D Labs maybe for 66389-31-9

Jiangxi Dongxu Chemical Science & Technology Co.,Ltd

Contact:+86-791-86899381

Address:Nanchang, Jiangxi, China
NINGBO YINLIANG FOREIGN TRADE CO., LTD.

Contact:+86-574-87834016 / 87898057

Address:23F NO.666JINYU ROAD,YINGZHOU DISTRICT,NINGBO.CHINA
Tianjin Te-An Chemtech Co., Ltd.(expird)

Contact:+86-22-65378638

Address:A5-8, No.80 Haiyun Street, TEDA
Zhejiang Kente Chemical Co.,Ltd.

Contact:86-0576-87651912

Address:No.7, Fengxi West Road, Modern Industrial Zone
Chengdu Gelipu Biotechnology Co., Ltd.

website:http://www.glp-china.com

Contact:86-28-82610909

Address:chegndu

Relevant to this article

A clean and one-pot synthesis of spiroindoline-pyranopyrazoles

Doi:10.1002/jhet.437
(2010)
Synthesis, characterization and biological activity of transition metal complexes with Schiff bases derived from 2-nitrobenzaldehyde with glycine and methionine

Doi:10.1016/j.saa.2012.03.077
(2012)
Base catalyzed cyclization of N-aryl and N-alkyl-O-propargyl carbamates to 4-alkylidene-2-oxazolidinones

Doi:10.1016/j.tet.2007.06.066
(2007)
Dismutation reactions of nucleoside polyphosphates. V. Syntheses of P,P-di(guanosine5') tetraphosphate and P,P-di(guanosine-5') triphosphate.

Doi:10.1021/ja00956a042
(1966)
A_2B Adenosine Receptor Antagonists with Picomolar Potency

Doi:10.1021/acs.jmedchem.9b00071
(2019)
Design, synthesis and insecticidal activity of novel analogues of flubendiamide containing alkoxyhexafluoroisopropyl groups

Doi:10.1039/d0ra07121h
(2020)

Article Doi