Efficient Preparation of Some Biologically Active Substances from Natural and Nonnatural Aromatic Compounds by m-Chloroperbenzoic Acid Oxidation

DOI: 10.1021/jo00258a010

Source and publish data:

Journal of Organic Chemistry p. 5453 - 5457 (1988)

Update date:2022-08-04

Topics:

Authors:

Asakawa, Yoshinori

Matsuda, Reiko

Tori, Motoo

Sono, Masakazu

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Article abstract of DOI:10.1021/jo00258a010

Six naturally occurring aromatic terpenoids and six nonnatural aromatic compounds were oxidized by m-chloroperbenzoic acid in chloroform to give 1,2- and 1,4-quinones or hydroxylated products in which vitamin K₁, insecticidal, piscicidal, and antifungal compounds were included.The present method is advantageous for obtaining different types of natural or nonnatural aromatic products having biological activity from the starting aromatic compounds in a one-step reaction.

Full text of DOI:10.1021/jo00258a010

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