Bonding isomerism in the η1-P coordination of the P4X3 (X=S, Se) molecules toward 16e rhodium fragments stabilized by tripodal tetradentate ligands

Article abstract of DOI:10.1016/j.jorganchem.2003.09.048

The reaction of tetraphosphorus trichalcogenides P₄X₃ (X=S, Se) with the electronically and coordinatively unsaturated 16 electron systems [(EP₃)Rh]⁺ [E=N, NP₃=tris (2-diphenylphosphanylethyl)amine, (