Tetrahedron Letters p. 381 - 382 (1986)
Update date:2022-08-02
Topics:
Bellesia, Franco
Ghelfi, Franco
Pagnoni, Ugo M.
Pinetti, Adriano
Base treatment of 10-oxocitral (1) gives chrysomelidial (9) and dehydroiridodial (10), supporting the intermediacy of 1 in the biosynthesis of some iridoid glucosides.Cannizzaro reaction of 9 and 10 affords regioselectively a new iridolactone, 1,2-dehydroisoiridomirmecin (13).
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(1988)
