THE BASE-CATALYZED CYCLIZATION OF 10-OXOCITRAL. SYNTHESIS OF CHRYSOMELIDIAL AND DEHYDROIRIDODIAL

DOI: 10.1016/S0040-4039(00)84024-1

Source and publish data:

Tetrahedron Letters p. 381 - 382 (1986)

Update date:2022-08-02

Topics:

Authors:

Bellesia, Franco

Ghelfi, Franco

Pagnoni, Ugo M.

Pinetti, Adriano

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)84024-1

Base treatment of 10-oxocitral (1) gives chrysomelidial (9) and dehydroiridodial (10), supporting the intermediacy of 1 in the biosynthesis of some iridoid glucosides.Cannizzaro reaction of 9 and 10 affords regioselectively a new iridolactone, 1,2-dehydroisoiridomirmecin (13).

Full text of DOI:10.1016/S0040-4039(00)84024-1

Products guided by the article

Product name:Epichrysomelidial

Cas No:66537-23-3

R&D Labs maybe for 66537-23-3

Watson International Ltd

Contact:+44 (0)2036089360-31

Address:Chanceryhouse,Chancery Lan
Angelisun(Chongqing) Pharmaceutical Co., LTD.

Contact:+86-23-68030926-816

Address:D1-7 Tech & Entrepreneurs Park, Kecheng Road, Erlang Hi-Tech Areas, Chongqing, China
Changzhou Anyi Biochem Co., Ltd.(expird)

Contact:+86-519-88836158

Address:no,51 caoda
Shanghai Gsyn Chemical Co.,Ltd.

Contact:86-021-67158290

Address:86-021-67158291
Hangzhou Gangjin Chemical Co.,Ltd.(expird)

Contact:+86-571-85109780

Address:707 Zhejiang Minhang Bldg., No.290 Zhongshan North Road, Hangzhou 310003, China

Relevant to this article

Design and synthesis of novel furan, furo[2,3-d]pyrimidine and furo[3,2-e][1,2,4]triazolo[1,5-c]pyrimidine derivatives as potential VEGFR-2 inhibitors

Doi:10.1016/j.bioorg.2021.105336
(2021)
Convenient access to substituted acridines by a Buchwald-Hartwig amination

Doi:10.1016/j.tet.2004.05.013
(2004)
10-Piperazinyl-4H-theino[3,2-b][1,5]- and -[3,4-b][1,5]benzodiazepines as potential neuroleptics.

Doi:10.1021/jm00182a014
(1980)
Syntheses, crystal structures and magnetic behaviors of three Mn^II-terephthalate coordination polymers containing terminal ligands

Doi:10.1016/j.poly.2008.04.029
(2008)
Design and regioselective synthesis of a new generation of targeted chemotherapeutics. Part 1: EC145, a folic acid conjugate of desacetylvinblastine monohydrazide

Doi:10.1016/j.bmcl.2006.07.030
(2006)
New Application of Solid Acid to Carbon-Carbon Bond Formation Reactions: Clay Montmorillonite-Catalyzed Aldol Reactions of Silyl Enol Ethers with Aldehydes and Acetals

Doi:10.1246/bcsj.61.1237
(1988)

Article Doi